Rational design and gas-phase characterization of molecular capsules by self-assembly of a symmetric hexasubstituted benzene with seven-membered lactams

被引：18

作者：

Baillargeon, Pierre ^{[1
]}

Dory, Yves L. ^{[1
]}

机构：

[1] Univ Sherbrooke, Inst Pharmacol, Dept Chim, Lab Synth Supramol, Sherbrooke, PQ J1H 5N4, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 17期

关键词：

D O I：

10.1021/ja800734b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel very simple C-3-symmetric lactam has been rationally designed to self-assemble as dimers or larger platonic solid capsules. Its core flat benzene ring bears three seven-membered lactams, resulting I in tripod molecules that aggregate into robust tetrameric capsules. The self-assembly process was templated by tetraethylammonium cations and proven to be reversible by ESI spectroscopy in various solvents.

引用

页码：5640 / +

页数：3

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