Synthesis of Binary Transition Metal Nitrides, Carbides and Borides from the Elements in the Laser-Heated Diamond Anvil Cell and Their Structure-Property Relations

被引：97

作者：

Friedrich, Alexandra ^{[1
]}

Winkler, Bjoern ^{[1
]}

Juarez-Arellano, Erick A. ^{[2
]}

Bayarjargal, Lkhamsuren ^{[1
]}

机构：

[1] Goethe Univ Frankfurt, Inst Geowissensch, Abt Kristallog, D-60438 Frankfurt, Germany

[2] Univ Papaloapan, Tuxtepec 68301, Oaxaca, Mexico

来源：

MATERIALS | 2011年 / 4卷 / 10期

关键词：

carbide; nitride; boride; transition metal; laser heating; diamond anvil cell; synthesis; extreme conditions; high pressure; high temperature; AUTOMATED DIFFRACTION TOMOGRAPHY; SUPERHARD RHENIUM DIBORIDE; X-RAY-DIFFRACTION; HIGH-TEMPERATURE SYNTHESIS; HIGH-PRESSURE SYNTHESIS; IN-SITU OBSERVATION; EQUATION-OF-STATE; ELASTIC-CONSTANTS; CRYSTAL-STRUCTURE; ELECTRONIC-STRUCTURE;

D O I：

10.3390/ma4101648

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transition metal nitrides, carbides and borides have a high potential for industrial applications as they not only have a high melting point but are generally harder and less compressible than the pure metals. Here we summarize recent advances in the synthesis of binary transition metal nitrides, carbides and borides focusing on the reaction of the elements at extreme conditions generated within the laser-heated diamond anvil cell. The current knowledge of their structures and high-pressure properties like high-(p,T) stability, compressibility and hardness is described as obtained from experiments.

引用

页码：1648 / 1692

页数：45

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