A new sodium hydroxygallophosphate containing tetrameric gallium units:: Na3[Ga4O(OH)(H2O)(PO4)4] • H2O

被引：3
作者：
Guesdon, A [1 ]
Monnin, Y [1 ]
Raveau, B [1 ]
机构：
[1] ISMRA Univ Caen, CNRS, UMR 6508, Lab CRISMAT, F-14050 Caen, France
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2004年 / 177卷 / 01期
关键词：
sodium gallium monophosphate; three-dimensional tunnel structure; tetrameric building units; hydrothermal synthesis; structure determination; single crystal; X-ray diffraction;
D O I：
10.1016/S0022-4596(03)00397-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new sodium hydroxygallophosphate, Na3Ga4O(OH)(H2O)(PO4)(4).H2O, has been prepared by hydrothermal synthesis. Its structure has been determined from a single-crystal X-ray diffraction study. It crystallizes in the P2(1)/c space group with the cell parameters a = 9.445(2) Angstrom, b = 9.028(1) Angstrom, c = 19.209(3) Angstrom, beta = 102.08(2), V = 1603.4(4) Angstrom(3). Its three-dimensional framework can be described from PO4 monophosphate groups sharing their apices with original Ga4O14(OH)(H2O) tetrameric building units, which result from the assembly of one GaO4 tetrahedron, one GaO5 trigonal bipyramid and two octahedra: GaO5(OH) and GaO4(OH)(H2O). The sodium cations and one water molecule are located in tunnels running along b. (C) 2003 Elsevier Inc. All rights reserved.
引用
收藏
页码：181 / 188
页数：8
相关论文
共 50 条
[21]   Elaboration and characterization of a new phosphate Mg1.74Cu1.26(PO4)2?H2O with morphotropic structure [J].
Khmiyas, Jamal ;
Assani, Abderrazzak ;
Saadi, Mohamed ;
El Ammari, Lahcen .
MATERIALS TODAY-PROCEEDINGS, 2022, 58 :1069-1073
[22]   Crystal structures of two hydrated sodium chromates: Na2CrO4 x 10 H2O and Na2CrO4 x 1.5 H2O [J].
Kahlenberg, Volker .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2012, 227 (09) :621-628
[23]   HydrothermalSynthesisandCharacterizationofaNovelSupramolecularNetworkCompound[Co（IN）2（H2O）4]（IN=Isonicotinate） [J].
JIA Hongbin YU Jiehui DING Hong XU Jiqing YE Ling JING Weijie WANG Tiegang XU Jianing QU Xuejian and LI Zengchun College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University Changchun P R China Key Laboratory of Supramolecular Structure and Materials of Ministry of Education Jilin University Changchun P R China Department of Chemistry Inner Mongolia University for Nationalities Tongliao P R China .
Chemical Research in Chinese Universities, 2002, (04) :385-388
[24]   Crystal structure of [Rb0.24(H2O)0.76]VO(H2O)(PO4), a new monoclinic variety in the series of layered vanadyl phosphates [J].
Yakubovich, O. V. ;
Yakovleva, E. V. ;
Yapaskurt, V. O. ;
Dimitrova, O. V. .
CRYSTALLOGRAPHY REPORTS, 2014, 59 (02) :160-165
[25]   HydrothermalSynthesisandCrystalStructureofIronMolybdophosphateFe[Mo6O12（OH）3（H2PO4）(HPO4)2（PO4）]2-[Fe（2,2′-bipy）(H2O)2]2[Fe（2,2′-bipy）3]2·6H2O [J].
GUO HongXua b LIU ShiXionga c a Department of Chemistry Fuzhou University Fuzhou China b Department of Chemistry Zhangzhou Teachers College Zhangzhou China c State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China .
结构化学, 2005, (10) :1117-1122+1101
[26]   Synthesis and characterization of Hf(SO4)2(H2O)4 and Hf(SeO3)(SeO4)(H2O) [J].
Genieva, S. ;
Yankova, R. ;
Baikusheva-Dimitrova, G. ;
Halachev, N. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2016, 124 (03) :1595-1600
[27]   New process of preparation, structure, and physicochemical investigations of the new titanyl phosphate Ti2O(H2O)(PO4)2 [J].
Benmokhtar, S. ;
El jazoulia, A. ;
Chaminade, J. P. ;
Gravereau, P. ;
Menetrier, M. ;
Bouree, F. .
JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (10) :2713-2722
[28]   [Mg(H2O)4][(VO)2(PO4)2]: Crystal structure, DFT calculations, and catalytic activity [J].
Akouibaa, Mohamed ;
El Amin, Nouhaila ;
Soussi, Ahmed ;
El Bali, Brahim ;
Lachkar, Mohamed ;
Obbade, Said ;
Jouffret, Laurent .
SOLID STATE COMMUNICATIONS, 2024, 391
[29]   Hydrothermal Synthesis, Structure, and Electrochemical Properties of a Three-dimensional Vanadium-Nickel Phosphate (C2H10N2)4[H2Ni(H2O)2(VO)8(OH)4(PO4)8]•H2O [J].
Yin, Fan-Wen ;
Peng, Cheng-Dong ;
Li, Ya-Si ;
Zhuang, Ting-Ting ;
Zeng, Qing-Xin ;
Yuan, Zhan-Hui .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (3-4) :543-547
[30]   Dehydration of blodite, Na2Mg(SO4)2(H2O)4, and leonite, K2Mg(SO4)2(H2O)4 [J].
Balic-Zunic, Tonci ;
Birkedal, Renie ;
Katerinopoulou, Anna ;
Comodi, Paola .
EUROPEAN JOURNAL OF MINERALOGY, 2016, 28 (01) :33-42
12345