A new sodium hydroxygallophosphate containing tetrameric gallium units:: Na3[Ga4O(OH)(H2O)(PO4)4] • H2O

被引：3
|
作者：
Guesdon, A [1 ]
Monnin, Y [1 ]
Raveau, B [1 ]
机构：
[1] ISMRA Univ Caen, CNRS, UMR 6508, Lab CRISMAT, F-14050 Caen, France
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2004年 / 177卷 / 01期
关键词：
sodium gallium monophosphate; three-dimensional tunnel structure; tetrameric building units; hydrothermal synthesis; structure determination; single crystal; X-ray diffraction;
D O I：
10.1016/S0022-4596(03)00397-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new sodium hydroxygallophosphate, Na3Ga4O(OH)(H2O)(PO4)(4).H2O, has been prepared by hydrothermal synthesis. Its structure has been determined from a single-crystal X-ray diffraction study. It crystallizes in the P2(1)/c space group with the cell parameters a = 9.445(2) Angstrom, b = 9.028(1) Angstrom, c = 19.209(3) Angstrom, beta = 102.08(2), V = 1603.4(4) Angstrom(3). Its three-dimensional framework can be described from PO4 monophosphate groups sharing their apices with original Ga4O14(OH)(H2O) tetrameric building units, which result from the assembly of one GaO4 tetrahedron, one GaO5 trigonal bipyramid and two octahedra: GaO5(OH) and GaO4(OH)(H2O). The sodium cations and one water molecule are located in tunnels running along b. (C) 2003 Elsevier Inc. All rights reserved.
引用
收藏
页码：181 / 188
页数：8
相关论文
共 50 条
  • [1] K3[Fe3.26V0.74(OH)O(PO4)4(H2O)2]•2H2O: a synthetic leucophosphite
    Silva-Galaz, C.
    Saldias, M.
    Garland, M. T.
    Vega, A.
    Paredes-Garcia, V.
    Spodine, E.
    Venegas-Yazigi, D.
    JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (10) : 1830 - 1836
  • [2] Synthesis and Characterization of NH4V(Gly)3(PO4)2•H2O
    Wei, Bo
    Cao, Huiqun
    Sun, Jianmin
    Lv, Yujuan
    2009 3RD INTERNATIONAL CONFERENCE ON BIOINFORMATICS AND BIOMEDICAL ENGINEERING, VOLS 1-11, 2009, : 1000 - +
  • [3] A NOVEL POTASSIUM-RICH VARIANT OF TINSLEYITE, |K1.5(H2O)0.5| [Al2(OH){(OH)0.5(H2O)0.5}(PO4)2]
    Yakubovich, Olga V.
    Massa, Werner
    Dimitrova, Olga V.
    CANADIAN MINERALOGIST, 2012, 50 (02) : 559 - 569
  • [4] RE(SO4)[B(OH)4](H2O), RE(SO4)[B(OH)4](H2O)2, and RE(SO4)[B(OH)4](H2O)•H2O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures
    Wang, Wen-Wen
    Xu, Xiang
    Kong, Jin-Tao
    Mao, Jiang-Gao
    INORGANIC CHEMISTRY, 2018, 57 (01) : 163 - 174
  • [5] Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)2(H2O)2 and AGa2P2O7(OH)3(H2O) (A = K, Rb)
    Wang, Tianyou
    Wu, Chao
    Lin, Lin
    Huang, Zhipeng
    Humphrey, Mark G.
    Zhang, Chi
    JOURNAL OF SOLID STATE CHEMISTRY, 2020, 288
  • [6] Hydrothermal synthesis and spectra properties of compound Mn5(PO3(OH))2(PO4)2(H2O)4
    Wu, XY
    Zhang, HH
    Huang, CC
    Sun, RQ
    Yang, QY
    Lin, ZH
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24 (06) : 694 - 697
  • [7] Two caesium vanadium hydrogenphosphates with tunnelled structures: Cs2V2O3(PO4)(HPO4) and Cs2[(VO)3(HPO4)4(H2O)]•H2O
    Gautier, Romain
    Colin, Jean-Francois
    Le Fur, Eric
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2010, 66 : I12 - I15
  • [8] Hydrothermal synthesis and characterization of two mixed valence piperazine-vanadium phosphates:: (C4H12N2)(H3O)[(VOPO4)4(H2O)H2PO4]•3H2O and (C4H12N2)[(VO)(VO2)2(H2O)(PO4)2]
    Do, J
    Bontchev, RP
    Jacobson, AJ
    JOURNAL OF SOLID STATE CHEMISTRY, 2000, 154 (02) : 514 - 523
  • [9] Synthesis and Characterization of [M2(OH)2(C4O4)2(H2O)4]•2H2O (M = Al or Ga)
    Halis, Selda
    Reinsch, Helge
    Stock, Norbert
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (23): : 1340 - 1344
  • [10] Hydrothermal synthesis of KTi2(PO4)3, α-Ti(HPO4)2•H2O and γ-Ti(PO4)(H2PO4)•2H2O from a lepidocrocite-type titanate
    Kumada, Nobuhiro
    Imase, Akihito
    Yanagida, Sayaka
    Takei, Takahiro
    Miura, Akira
    Itoi, Nobuki
    Goto, Toshiki
    JOURNAL OF ASIAN CERAMIC SOCIETIES, 2019, 7 (03) : 361 - 367
12345