A Novel 3D Cobalt(II) Complex Constructed by 2,2′-(1,4-Butanediyl)bis(1H-benzimidazole) Ligand

被引：0
|
作者：
Pu Xiao-Hua [1 ]
Jiang Luan [1 ]
Wang Yan [1 ]
Feng Guo-Dong [1 ]
Zhao Wei-Xing [1 ]
机构：
[1] Baoji Univ Arts & Sci, Dept Chem & Chem Engn, Baoji 721013, Shaanxi, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 08期
关键词：
hydrothermal reaction; crystal structure; syntheses; 3D framework; CADMIUM(II); NETWORKS; DESIGN;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel 3D polymer 1 (C26H22CoN4O4, M-r = 513.41) constructed from H(2)C(4)BIm (2,2'-(1,4-butanediyl)bis(1H-benzimidazole)], 1,3-bdc (1,3-benzenedicarboxylate) and Co(II) has been successfully synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis. The crystal belongs to the tetragonal system, space group I-42d with a = 24.315(5), b = 24.315(5), c = 8.343(2) angstrom, V = 4933(2) angstrom(3), Z = 8, D-c = 1.383 g/cm(3), mu(MoK alpha) = 0.735 mm(-1), F(000) = 2120, S = 1.156, the final R = 0.0596 and wR = 0.1346 for 1529 reflections with I > 2 sigma(I). Complex 1 contains 1D chains which are connected by extensive hydrogen-bonding interactions to form the 2D folded layer and 3D framework, which also stabilize the structure.
引用
收藏
页码：1168 / 1172
页数：5
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