Interpretation of the excess adsorption isotherms of organic eluent components on the surface of reversed-phase phenyl modified adsorbents

被引：53

作者：

Chan, F

Yeung, LS

LoBrutto, R ^{[1
]}

Kazakevich, Y

机构：

[1] Nova Pharmaceut Corp, PHAD ARD, E Hanover, NJ 07936 USA

[2] Seton Hall Univ, Dept Chem & Biochem, S Orange, NJ 07079 USA

来源：

JOURNAL OF CHROMATOGRAPHY A | 2005年 / 1082卷 / 02期

关键词：

adsorption; reversed-phase; phenyl-type bonded phases;

D O I：

10.1016/j.chroma.2005.05.078

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The adsorption of three organic eluent components (acetonitrile, methanol, and tetrahydrofuran) from water were measured on four phenyltype bonded phases using the minor disturbance method. The thicknesses of organic layer enriched above the phenyl-type bonded ligands were assessed and interpreted. Acetonitrile and tetrahydrofuran showed multilayer formation while methanol showed monomolecular adsorption. These results were compared to those obtained on alkyl bonded phases. (c) 2005 Elsevier B.V All rights reserved.

引用

页码：158 / 165

页数：8

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