Poly[(μ2-quinoline-3-carboxylato-κ2N:O)(μ2-quinoline-3-carboxylato-κ3N:O,O′)cadmium]

被引:0
作者
Wang, Xing [1 ]
Yan, Yong-Sheng [1 ]
Sun, He-Yi [1 ]
Wang, Shen-Tang [1 ]
Liu, Chun-Bo [1 ]
机构
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词
COORDINATION POLYMERS; CRYSTAL-STRUCTURE;
D O I
10.1107/S1600536812001031
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cd(C10H6NO2)2](n), the Cd-II atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxylate (L-) ligands, leading to a distorted trigonal-bipyramidal geometry. The L- ligands link the Cd-II atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by pi-pi interactions, with centroid-centroid distances of 3.680 (2) and 3.752 (2) angstrom. Another type of pi-pi interaction between pyridine rings [centroid-centroid distance = 3.527 (2) angstrom] leads to a three-dimensional supramolecular architecture.
引用
收藏
页码:M163 / U785
页数:12
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