Distribution of polychlorinated dibenzo-p-dioxins and dibenzofurans in ambient air of different regions in China

被引:26
作者
Chen, Tong [1 ]
Li, Xiaodong [1 ]
Yan, Jianhua [1 ]
Lu, Shengyong [1 ]
Cen, Kefa [1 ]
机构
[1] Zhejiang Univ, Inst Thermal Power Engn, State Key Lab Energy Clean Utilizat, Hangzhou 310027, Zhejiang, Peoples R China
关键词
PCDD/Fs; Ambient air; Homologue profile; Congener profile; China; PCDD/F LEVELS; ATMOSPHERE; ENVIRONMENT; DEPOSITION; PCBS;
D O I
10.1016/j.atmosenv.2011.08.013
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Levels of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were determined in fourteen ambient air samples collected in twelve cities of five provinces and one large municipality in China. The PCDD/F concentrations varied from 2.6 to 120 pg m(-3) (or from 0.04 to 1.93 pg I-TEQ m(-3)). Generally, TCDF was the dominant homologue group and as a rule the homologue concentration of PCDF decreased with rising chlorine substitution number of PCDF. In all cases 2,3,4,7,8-PeCDF was the most important contributor to the I-TEQ value, accounting for 35-57% of the total I-TEQ value. Higher PCDD/F levels in ambient air were found during winter. The highest PCDD/F levels were found in Chengdu, Sichuan Province. In general, the PCDD/F levels in this study were in the same range as in other studies in China. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6567 / 6575
页数:9
相关论文
共 17 条
[1]   Evaluation of PCDD/F levels in ambient air and soils and estimation of deposition rates in Kocaeli, Turkey [J].
Bakoglu, M ;
Karademir, A ;
Durmusoglu, E .
CHEMOSPHERE, 2005, 59 (10) :1373-1385
[2]   Monitoring of ambient air PCDD/F levels in Portugal [J].
Coutinho, Miguel ;
Pereira, Margaret ;
Borrego, Carlos .
CHEMOSPHERE, 2007, 67 (09) :1715-1721
[3]   Dioxins and furans in the atmosphere of Sao Paulo City, Brazil [J].
de Assunçao, JV ;
Pesquero, UR ;
Bruns, RE ;
Carvalho, LRF .
CHEMOSPHERE, 2005, 58 (10) :1391-1398
[4]   Sources of PCDD/PCDF and impact on the environment [J].
Fiedler, H .
CHEMOSPHERE, 1996, 32 (01) :55-64
[5]   Ambient air monitoring of PCDD/Fs and co-PCBs in Gyeonggi-do, Korea [J].
Kim, Dong Gi ;
Min, Yoon Ki ;
Jeong, Ju Yong ;
Kim, Gu Hwan ;
Kim, Joo Yeol ;
Son, Chin Suk ;
Lee, Dona Hoon .
CHEMOSPHERE, 2007, 67 (09) :1722-1727
[6]   RATE CONSTANTS FOR THE GAS-PHASE REACTIONS OF THE OH RADICAL WITH DICHLOROBIPHENYLS, 1-CHLORODIBENZO-P-DIOXIN, 1,2-DIMETHOXYBENZENE, AND DIPHENYL ETHER - ESTIMATION OF OH RADICAL REACTION-RATE CONSTANTS FOR PCBS, PCDDS, AND PCDFS [J].
KWOK, ESC ;
ATKINSON, R ;
AREY, J .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1995, 29 (06) :1591-1598
[7]   Distribution of air and serum PCDD/F levels of electric arc furnaces and secondary aluminum and copper smelters [J].
Lee, Ching-Chang ;
Shih, Tung-Seng ;
Chen, Hsiu-Ling .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 172 (2-3) :1351-1356
[8]   The PCDD/F and PBDD/F pollution in the ambient atmosphere of Shanghai, China [J].
Li, Huiru ;
Feng, Haliang ;
Sheng, Guoying ;
Lue, Senlin ;
Fu, Jiamo ;
Peng, Ping'an ;
Man, Ren .
CHEMOSPHERE, 2008, 70 (04) :576-583
[9]   Concentrations, profiles and gas-particle partitioning of polychlorinated dibenzo-p-dioxins and dibenzofurans in the ambient air of Beijing, China [J].
Li, Yingming ;
Jiang, Guibin ;
Wang, Yawei ;
Cai, Zongwei ;
Zhang, Qinghua .
ATMOSPHERIC ENVIRONMENT, 2008, 42 (09) :2037-2047
[10]   Atmospheric distribution of polychlorinated dibenzo-p-dioxins, dibenzofurans and dioxin-like polychlorinated biphenyls around a steel plant Area, Northeast China [J].
Li, Yingming ;
Wang, Pu ;
Ding, Lei ;
Li, Xiaomin ;
Wang, Thanh ;
Zhang, Qinghua ;
Yang, Hongbiao ;
Jiang, Guibin ;
Wei, Fusheng .
CHEMOSPHERE, 2010, 79 (03) :253-258