A Two-Fold Interpenetrating Porous Metal-Organic Framework with a Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties

被引：17
|
作者：
Gong, Yun-Nan [1 ]
Xie, Yong-Rong [1 ]
Zhong, Di-Chang [1 ]
Du, Zi-Yi [1 ]
Lu, Tong-Bu [2 ]
机构：
[1] Gannan Normal Univ, Coll Chem & Chem Engn, Key Lab Jiangxi Univ Funct Mat Chem, Ganzhou 341000, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2015年 / 15卷 / 07期
关键词：
COORDINATION POLYMER; HYDROGEN; MOF; TRANSFORMATION; STORAGE;
D O I：
10.1021/acs.cgd.5b00634
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A luminescent porous metal-organic frame-work based on pi-electron-rich tricarboxylate has been solvothermally prepared and characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analyses, and single-crystal X-ray diffraction analysis. This compound is a 2-fold interpenetrating framework with a large solvent-accessible volume and exhibits gas sorption behaviors for N-2, H-2, and CO2 gases and relatively strong interactions between CO2 and the framework. Furthermore, it also shows interesting guest-responsive luminescent changes toward different solvent molecules.
引用
收藏
页码：3119 / 3122
页数：4
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