A Two-Fold Interpenetrating Porous Metal-Organic Framework with a Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties

被引：17
|
作者：
Gong, Yun-Nan [1 ]
Xie, Yong-Rong [1 ]
Zhong, Di-Chang [1 ]
Du, Zi-Yi [1 ]
Lu, Tong-Bu [2 ]
机构：
[1] Gannan Normal Univ, Coll Chem & Chem Engn, Key Lab Jiangxi Univ Funct Mat Chem, Ganzhou 341000, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2015年 / 15卷 / 07期
关键词：
COORDINATION POLYMER; HYDROGEN; MOF; TRANSFORMATION; STORAGE;
D O I：
10.1021/acs.cgd.5b00634
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A luminescent porous metal-organic frame-work based on pi-electron-rich tricarboxylate has been solvothermally prepared and characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analyses, and single-crystal X-ray diffraction analysis. This compound is a 2-fold interpenetrating framework with a large solvent-accessible volume and exhibits gas sorption behaviors for N-2, H-2, and CO2 gases and relatively strong interactions between CO2 and the framework. Furthermore, it also shows interesting guest-responsive luminescent changes toward different solvent molecules.
引用
收藏
页码：3119 / 3122
页数：4
相关论文
共 50 条
  • [21] Two-Fold Homointerpenetrated Metal-Organic Framework with the Potential for Anticancer Drug Loading Using Computational Simulations
    Alavijeh, Roya Karimi
    Akhbari, Kamran
    Tylianakis, Emmanuel
    Froudakis, George E.
    White, Jonathan M.
    CRYSTAL GROWTH & DESIGN, 2021, 21 (11) : 6402 - 6410
  • [22] Highly selective fluorescent probe for Hg2+ and MnO4- by the two-fold interpenetrating metal-organic framework with nitro functionalized linkers
    Li, Fan
    Hong, Yun-Si
    Zuo, Kai-Xi
    Sun, Qian
    Gao, En-Qing
    JOURNAL OF SOLID STATE CHEMISTRY, 2019, 270 : 509 - 515
  • [23] Geometrical and functional properties of organic ligands on gas sorption properties of metal-organic framework materials
    Trieu, Thuong
    Zhao, Xiang
    Bu, Xianhui
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [24] Unprecedented (3,4)-connected metal-organic frameworks (MOFs) with 3-fold interpenetration and considerable solvent-accessible void space
    Luo, Feng
    Zheng, Ji-Min
    Batten, Stuart R.
    CHEMICAL COMMUNICATIONS, 2007, (36) : 3744 - 3746
  • [25] Assembly of two new self-interpenetrating metal-organic frameworks with tunable luminescent properties
    Luo, Yu-Hui
    Tan, Xue-Qi
    Chen, Feng-Yu
    Liu, Zhi-Yong
    Li, Jie
    Yang, Yun-Qiong
    POLYHEDRON, 2024, 249
  • [26] Synthesis and gas sorption properties of a homochiral metal-organic framework with octahedral cages
    Xu, Zhong-Xuan
    Wu, Xin
    Liu, Juan
    Kang, Yao
    Zhang, Jian
    CRYSTENGCOMM, 2015, 17 (32): : 6107 - 6109
  • [27] Porous metal-organic framework based on μ4-oxo tetrazinc clusters:: Sorption and guest-dependent luminescent properties
    Hou, Lei
    Lin, Yan-Yong
    Chen, Xiao-Ming
    INORGANIC CHEMISTRY, 2008, 47 (04) : 1346 - 1351
  • [28] Two-Fold Interpenetrated Binuclear Nickel Metal-Organic Framework as a Heterogeneous Catalyst for N-Heterocycle Synthesis
    Tan, Ke-Xin
    Li, Ke
    Zheng, Zhi-Jian
    Lin, Xiao-Ling
    Liu, Yu-Feng
    Zhang, Zhi-Bin
    Yang, Guo-Ping
    INORGANIC CHEMISTRY, 2023, 62 (42) : 17310 - 17316
  • [29] Synthesis of an exceptional water-stable two-fold interpenetrated Zn(II)-paddlewheel metal-organic framework
    Wang, Jingjing
    Zhang, Jun
    Jin, Fengyan
    Luo, Yanping
    Wang, Shufen
    Zhang, Zaiyong
    Wu, Yong
    Liu, Hongke
    Luc, Jack Y.
    Fang, Min
    CRYSTENGCOMM, 2015, 17 (31): : 5906 - 5910
  • [30] A New 3-Fold Interpenetrating 3D Zn(Ⅱ) Metal-organic Framework: Synthesis,Structure and Luminescent Property
    苗少斌
    李召好
    许春莺
    吉保明
    结构化学, 2016, 35 (12) : 1960 - 1966
12345