A Two-Fold Interpenetrating Porous Metal-Organic Framework with a Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties

被引：17

作者：

Gong, Yun-Nan ^{[1
]}

Xie, Yong-Rong ^{[1
]}

Zhong, Di-Chang ^{[1
]}

Du, Zi-Yi ^{[1
]}

Lu, Tong-Bu ^{[2
]}

机构：

[1] Gannan Normal Univ, Coll Chem & Chem Engn, Key Lab Jiangxi Univ Funct Mat Chem, Ganzhou 341000, Peoples R China

[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2015年 / 15卷 / 07期

关键词：

COORDINATION POLYMER; HYDROGEN; MOF; TRANSFORMATION; STORAGE;

D O I：

10.1021/acs.cgd.5b00634

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A luminescent porous metal-organic frame-work based on pi-electron-rich tricarboxylate has been solvothermally prepared and characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analyses, and single-crystal X-ray diffraction analysis. This compound is a 2-fold interpenetrating framework with a large solvent-accessible volume and exhibits gas sorption behaviors for N-2, H-2, and CO2 gases and relatively strong interactions between CO2 and the framework. Furthermore, it also shows interesting guest-responsive luminescent changes toward different solvent molecules.

引用

页码：3119 / 3122

页数：4

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