Alkanol effects on fluorescence quenching of Safranine T by thiourea in reverse micellar medium of Aerosol-O-T in heptane

被引:13
作者
Nandi, S [1 ]
Bhattacharya, SC [1 ]
机构
[1] Jadavpur Univ, Dept Chem, Chem Phys Sect, Kolkata 700032, W Bengal, India
关键词
fluoresecence quenching; reverse micelle; Safranine T; alkanol;
D O I
10.1016/S0927-7757(00)00822-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fluorescence characteristics of Safranine: T (ST) (3,6-diamino-2,7-dimethyl-5 phenyl phenazinium chloride) in presence of thiourea have been studied in reverse micelles of Aerosol-O-T in heptane and in presence of alkanols. From the results of the fluorescence quenching of ST by thiourea the occupancy number of the quencher in the reverse micelle (RM), and the binding constant of the quencher with the RM have been determined using Encinas-Lissi equation. The alkanols added are found to affect the quenching process. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:179 / 187
页数:9
相关论文
共 26 条
[11]  
Fendler J. H., 1975, CATALYSIS MICELLAR M, P386
[12]   FLUORESCENCE QUENCHING OF ACRIDINE-ORANGE BY AROMATIC-AMINES IN CATIONIC, ANIONIC AND NONIONIC MICELLES [J].
GEHLEN, MH ;
FO, PB ;
NEUMANN, MG .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 59 (03) :335-340
[13]   SPECIFIC QUENCHING OF THE PHOTOEXCITED STATE OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) BY COLLOIDAL PRUSSIAN BLUE [J].
KANEKO, M ;
HOU, XH ;
YAMADA, A .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :1637-1642
[14]   STUDIES ON THE TRITON X-100 - ALCOHOL - WATER REVERSE MICELLES IN CYCLOHEXANE [J].
KUMAR, C ;
BALASUBRAMANIAN, D .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1979, 69 (02) :271-279
[15]  
KUZUMIN MG, 1995, J PHOTOCH PHOTOBIO A, V87, P43
[16]  
Lang J., 1990, STRUCTURE DYNAMICS E, P253
[17]   MICELLAR INTERACTIONS IN WATER-IN-OIL MICROEMULSIONS .1. CALCULATED INTERACTION POTENTIAL [J].
LEMAIRE, B ;
BOTHOREL, P ;
ROUX, D .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (06) :1023-1028
[18]   SOLUBILIZATION AND PHASE-EQUILIBRIA OF WATER-IN-OIL MICROEMULSIONS .2. EFFECTS OF ALCOHOLS, OILS, AND SALINITY ON SINGLE-CHAIN SURFACTANT SYSTEMS [J].
LEUNG, R ;
SHAH, DO .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1987, 120 (02) :330-344
[19]   VIBRATIONAL SPECTROSCOPIC STUDY OF THE STRUCTURE OF SODIUM BIS(2-ETHYLHEXYL)SULFOSUCCINATE REVERSE MICELLES AND WATER-IN-OIL MICROEMULSIONS [J].
MORAN, PD ;
BOWMAKER, GA ;
COONEY, RP ;
BARTLETT, JR ;
WOOLFREY, JL .
LANGMUIR, 1995, 11 (03) :738-743
[20]  
Moulik S. P., 1996, P INDIAN NATL SCI A, V62, P215