Click Approaches to Functional Water-Sensitive Organotriethoxysilanes

被引：48
作者：
Buerglova, Kristyna [1 ,2 ]
Moitra, Nirmalya [1 ]
Hodacova, Jana [2 ]
Cattoen, Xavier [1 ]
Man, Michel Wong Chi [1 ]
机构：
[1] UMR 5253 CNRS UM2 ENSCM UM1, Inst Charles Gerhardt Montpellier, F-34296 Montpellier, France
[2] Inst Chem Technol, Dept Organ Chem, CR-16628 Prague 6, Czech Republic
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 18期
关键词：
HYBRID SILICA; LIGANDS; SILSESQUIOXANES; OPTIMIZATION; DERIVATIVES; CHEMISTRY; CATALYSIS; ADENINE; UNITS; SIZE;
D O I：
10.1021/jo201484n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The derivatization of functional organic fragments with triethoxysilyl groups to afford hydrolyzable organosilanes with targeted properties using the copper-catalyzed alkyne azide cydoaddition reaction under strictly anhydrous conditions is described according to two approaches, starting from five silylated substrates. This high yield, fast, and selective method is applicable to a wide range of substrates and is expected to lead to important achievements in the field of functional hybrid silica.
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收藏
页码：7326 / 7333
页数：8
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