Click Approaches to Functional Water-Sensitive Organotriethoxysilanes

被引：48

作者：

Buerglova, Kristyna ^{[1
,2
]}

Moitra, Nirmalya ^{[1
]}

Hodacova, Jana ^{[2
]}

Cattoen, Xavier ^{[1
]}

Man, Michel Wong Chi ^{[1
]}

机构：

[1] UMR 5253 CNRS UM2 ENSCM UM1, Inst Charles Gerhardt Montpellier, F-34296 Montpellier, France

[2] Inst Chem Technol, Dept Organ Chem, CR-16628 Prague 6, Czech Republic

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 18期

关键词：

HYBRID SILICA; LIGANDS; SILSESQUIOXANES; OPTIMIZATION; DERIVATIVES; CHEMISTRY; CATALYSIS; ADENINE; UNITS; SIZE;

D O I：

10.1021/jo201484n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The derivatization of functional organic fragments with triethoxysilyl groups to afford hydrolyzable organosilanes with targeted properties using the copper-catalyzed alkyne azide cydoaddition reaction under strictly anhydrous conditions is described according to two approaches, starting from five silylated substrates. This high yield, fast, and selective method is applicable to a wide range of substrates and is expected to lead to important achievements in the field of functional hybrid silica.

引用

页码：7326 / 7333

页数：8

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