The allenic derivatives of biologically active natural sesquiterpenes were synthesized by two reaction sequence: addition of Seyferth reagent producing dibromocyclopropanes then the allenic derivative formation by Hiyama reaction. The structure of all products was determined using H-1 and C-13 NMR.
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Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
Brock Univ, Ctr Biotechnol, St Catharines, ON L2S 3A1, CanadaBrock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
Ohnmacht, Stephan
West, Ryan
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Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
Brock Univ, Ctr Biotechnol, St Catharines, ON L2S 3A1, CanadaBrock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
West, Ryan
Sirnionescu, Razvan
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Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
Brock Univ, Ctr Biotechnol, St Catharines, ON L2S 3A1, CanadaBrock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
Sirnionescu, Razvan
Atkinson, Jeffrey
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Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
Brock Univ, Ctr Biotechnol, St Catharines, ON L2S 3A1, CanadaBrock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada