1H and 13C NMR of synthetic allenic derivatives from eudesmanolides and pseudoguayanolides

被引:6
|
作者
Diaz, E
Ortega, A
Guerrero, C
Guzman, A
Lizama, BE
Benitez, AF
Jankowski, CK
机构
[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico
[2] UAEM Toluca, Fac Quim, Toluca, Mexico
来源
NATURAL PRODUCT LETTERS | 1998年 / 12卷 / 04期
关键词
D O I
10.1080/10575639808048298
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The allenic derivatives of biologically active natural sesquiterpenes were synthesized by two reaction sequence: addition of Seyferth reagent producing dibromocyclopropanes then the allenic derivative formation by Hiyama reaction. The structure of all products was determined using H-1 and C-13 NMR.
引用
收藏
页码:241 / 254
页数:14
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