Fixation of CO2 by pyrazolylborate-zinc-hydroxide complexes

被引：8

作者：

Peter, A ^{[1
]}

Vahrenkamp, H ^{[1
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 12期

关键词：

zinc; hydroxide complexes; pyrazolylborate complexes; CO2; chemistry; insertion;

D O I：

10.1002/zaac.200500196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reversible uptake Of CO2 by Tp*Zn-OH complexes in alcoholic solutions with formation of Tp*Zn-alkylcarbonate complexes was subjected to a comparative study. Its rate and the stability of its products depend on (1) the substituents in the 3-positions of the pyrazolylborates (phenyl approximate to 3-pyridyl >> t-butyl), (2) the alcohol (CH3OH > C2H5OH). Traces of water seem to be essential for the formation of the Tp*Zn-alkylcarbonates. In solution these are only stable in the presence Of CO2. Two new alkylcarbonate complexes were obtained and characterized by structure determinations.

引用

页码：2347 / 2351

页数：5

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