Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2•BPh4

被引：28

作者：

Benedict, Jason B. ^{[1
]}

Makal, Anna ^{[1
]}

Sokolow, Jesse D. ^{[1
]}

Trzop, Elzbieta ^{[1
]}

Scheins, Stephan ^{[2
]}

Henning, Robert ^{[3
]}

Graber, Timothy ^{[3
]}

Coppens, Philip ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

[2] Univ Aarhus, Dept Chem, DK-8000 Aarhus C, Denmark

[3] Univ Chicago, Consortium Adv Radiat Sources, Chicago, IL 60637 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 06期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

X-RAY-DIFFRACTION; SOLID-STATE; CRYSTALLOGRAPHY; ION;

D O I：

10.1039/c0cc04997b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) angstrom is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.

引用

页码：1704 / 1706

页数：3

共 17 条

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