Hydroxytyrosol (HT), tyrosol (TY), and oleuropein (OL) are valuable compounds that can be obtained from olive oil production waste. This study implemented liquid-liquid extraction to obtain HT, TY, and OL from model solutions using two organic solvents, namely, ethyl acetate and n-butyl acetate, and three ionic liquids (ILs), namely, [P-6,P-6,P-6,P-14][Tf2N], [P-6,P-6,P-6,P-14][DCA], and [omim][Tf2N]. [P-6,P-6,P-6,P-14][DCA] showed the best performance, with extraction efficiencies of 92%, 96%, and 83% for HT, TY, and OL, respectively. [omim][Tf2N] showed the highest selectivity in the extraction of TY. Comparisons of the results of a proposed mathematical model with experimental data yielded errors lower than 0.5%.