Tremella derived ultrahigh specific surface area activated carbon for high performance supercapacitor

被引:67
作者
Guo, Nannan [1 ]
Li, Min [1 ]
Sun, Xingkai [1 ]
Wang, Feng [1 ]
Yang, Ru [1 ]
机构
[1] Beijing Univ Chem Technol, Beijing Key Lab Electrochem Proc & Technol Mat, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Tremella; Ultrahigh specific surface area; Activated carbon; Supercapacitor; HIERARCHICALLY POROUS CARBON; HYDROTHERMAL CARBONIZATION; ELECTRODE MATERIAL; ENERGY-STORAGE; BATTERY ANODES; PORE STRUCTURE; IONIC LIQUIDS; SOLAR-CELLS; NITROGEN; NANOSHEETS;
D O I
10.1016/j.matchemphys.2017.08.054
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Activated carbons derived from sustainable biomass have attracted widespread attention as electrode materials for supercapacitors due to their economic value, tunable physical/chemical properties and environmental concern. Tremella, renewable and abundant biomass, has been explored as precursor to prepare hierarchical activated carbons by means of carbonization and KOH activation. The obtained sample possesses an ultrahigh BET specific surface area of 3760 m(2) g(-1) and very high mesopore volume ratio of 72%. So, the sample shows a superior specific capacitance 71 F g(-1) at 1 A g(-1); extraordinary rate performance with a capacitance of 53.5 F g(-1) at 30 A g(-1); outstanding cycle stability with 99% capacitance retention after 10,000 galvanostatic charge-discharge cycles at 5 A g(-1) in a symmetric two electrode supercapacitor with 6 M KOH solution as electrolyte. The assembled supercapacitor shows a superior energy density of 65.6 W h kg (-1) in ionic liquid electrolyte system and 28 W h kg (-1) is still maintained even at an ultrahigh power density 19,700 W kg (-1).(C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:399 / 407
页数:9
相关论文
共 60 条
[1]   Capacitive performance of cysteamine functionalized carbon nanotubes [J].
Ali, Gomaa A. M. ;
Teo, Ellie Yi Lih ;
Aboelazm, Eslam A. A. ;
Sadegh, Hamidreza ;
Memar, Amir O. H. ;
Shahryari-Ghoshekandi, Ramin ;
Chong, Kwok Feng .
MATERIALS CHEMISTRY AND PHYSICS, 2017, 197 :100-104
[2]   High performance MnO2 nanoflower supercapacitor electrode by electrochemical recycling of spent batteries [J].
Ali, Gomaa A. M. ;
Yusoff, Mashitah M. ;
Shaaban, Essam R. ;
Chong, Kwok Feng .
CERAMICS INTERNATIONAL, 2017, 43 (11) :8440-8448
[3]  
Ali GAM, 2015, REV ADV MATER SCI, V41, P35
[4]   Co3O4/SiO2 nanocomposites for supercapacitor application [J].
Ali, Gomaa A. M. ;
Fouad, Osama A. ;
Makhlouf, Salah A. ;
Yusoff, Mashitah M. ;
Chong, Kwok Feng .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2014, 18 (09) :2505-2512
[5]  
Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]
[6]   Waste Cleaning Waste: Photodegradation of Monochlorophenols in the Presence of Waste-Derived Photosensitizer [J].
Avetta, P. ;
Bella, F. ;
Prevot, A. Bianco ;
Laurenti, E. ;
Montoneri, E. ;
Arques, A. ;
Carlos, L. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2013, 1 (12) :1545-1550
[7]   Paper-based quasi-solid dye-sensitized solar cells [J].
Bella, Federico ;
Pugliese, Diego ;
Zolin, Lorenzo ;
Gerbaldi, Claudio .
ELECTROCHIMICA ACTA, 2017, 237 :87-93
[8]   Approaching truly sustainable solar cells by the use of water and cellulose derivatives [J].
Bella, Federico ;
Galliano, Simone ;
Falco, Marisa ;
Viscardi, Guido ;
Barolo, Claudia ;
Gratzel, Michael ;
Gerbaldi, Claudio .
GREEN CHEMISTRY, 2017, 19 (04) :1043-1051
[9]   Ionic liquids in supercapacitors [J].
Brandt, A. ;
Pohlmann, S. ;
Varzi, A. ;
Balducci, A. ;
Passerini, S. .
MRS BULLETIN, 2013, 38 (07) :554-559
[10]  
Chen CJ, 2017, ENERG ENVIRON SCI, V10, P538, DOI [10.1039/c6ee03716j, 10.1039/C6EE03716J]