Enantioselective Rhodium-Catalyzed [4+2] Cycloaddition of α,β-Unsaturated Imines and Isocyanates

被引：41

作者：

Oberg, Kevin M. ^{[1
]}

Rovis, Tomislav ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 13期

关键词：

DIELS-ALDER REACTIONS; ALKENYL ISOCYANATES; ASYMMETRIC-SYNTHESIS; TERMINAL ALKYNES; 1-AZADIENES; INSERTION; NICKEL(0);

D O I：

10.1021/ja200766k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A [4 + 2] cycloaddition of alpha,beta-unsaturated imines and isocyanates catalyzed by a phosphoramidite rhodium complex provides pyrimidinones in good yields and high enantioselectivities.

引用

页码：4785 / 4787

页数：3

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