Direct Synthesis of Cd3OSO4 Nano-particles From a New Three-dimensional Cadmium(II) Coordination Polymer Precursor

被引：7

作者：

Shahverdizadeh, Gholam Hossein ^{[1
]}

Masoudian, Shahla ^{[2
]}

Soudi, Ali Akbar ^{[2
]}

Bigdeli, Fahime ^{[3
]}

Monfared, Hassan Hosseini ^{[2
]}

Morsali, Ali ^{[4
]}

Khavasi, Hamid Reza ^{[5
]}

机构：

[1] Islamic Azad Univ, Dept Appl Chem, Res Lab, Tabriz Branch, Tabriz, Iran

[2] Zanjan Univ, Dept Chem, Zanjan, Iran

[3] Payame Noor Univ, Dept Chem, Abhar, Iran

[4] Tarbiat Modares Univ, Dept Chem, Fac Sci, Tehran, Iran

[5] Shahid Beheshti Univ, Dept Chem, Tehran, Iran

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2011年 / 21卷 / 01期

关键词：

Crystal structure; Thermal properties; Nano-materials; Cadmium(II); RAY CRYSTAL-STRUCTURE; COMPLEXES; CDO; CHEMISTRY; CD(OH)(2); LIGANDS; IONS;

D O I：

10.1007/s10904-010-9443-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new three-dimensional Cd(II) coordination polymer, {[Cd-3(3-pyc)(4)(NCS)(2)(H2O)(4)]center dot 2H(2)O} (n) (1); 3-Hpyc = 3-pyridinecarboxylic acid, was prepared and characterized by elemental analyses and IR spectroscopy. Compound 1 was structurally characterized by single-crystal X-ray diffraction. The structural determination shows that the compound is a new 3D coordination polymer has different environments containing CdO5NS and CdO2N4 units. This polymeric precursor has been used in the preparation of Cd3OSO4 nanoparticles by thermolysis in oleic acid. The new nano-structure of Cd3OSO4 was characterized by scanning electron microscopy and X-ray powder diffraction. This study demonstrates that coordination polymers may be suitable precursors to the preparation of desirable nanoscale materials.

引用

页码：171 / 174

页数：4

共 50 条

[41] Sonochemical Synthesis and Characterization of A Nano-Rod Lead(II) Supramolecular, Three Dimensional Coordination Compound: New Precursor to Produce Pure Phase Nano-Sized Lead(II) Oxide
Hanifehpour, Younes
Mirtamizdoust, Babak
Joo, Sang Woo
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2012, 22 (05) : 952 - 956
[42] Synthesis and crystal structure of a new three-dimensional Ho(II) coordination polymer based on 5'-(4-Carboxyphenyl)-[1,1':3',1"-terphenyl]-4,4"-dicarboxylic acid
Li, Shi-Hui
Zang, Jia
Guo, Jin-Bo
INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (12) : 1746 - 1749
[43] Synthesis, structure and adsorption properties of a three-dimensional 3-fold interpenetrated Cd(II) coordination network with the rare tfz topology
Cheng, Pei-Chi
Lo, Yang-Chih
Hsu, Wayne
Thapa, Kedar Bahadur
Liou, Shih-Miao
Chen, Jhy-Der
POLYHEDRON, 2015, 96 : 1 - 5
[44] Sonochemical Synthesis of New Nano-Belt One-Dimensional Double-Chain Lead(II) Coordination Polymer; As Precursor for Preparation of PbBr(OH) Nano-Structure
Mohammad Jaafar Soltanian Fard
Ali Morsali
Journal of Inorganic and Organometallic Polymers and Materials, 2010, 20 : 727 - 732
[45] A one-dimensional coordination polymer with a three-dimensional supramolecular framework: catena-poly[[[(3,4,7,8-tetramethyl-1,10-phenanthroline) cadmium(II)]-μ3-4,4′-sulfonyldibenzoato] trihydrate]
Wang, Jun
Tao, Jian-Qing
Xu, Xiao-Juan
Tan, Chun-Yun
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2013, 69 : 241 - U102
[46] A three-dimensional cadmium(II) coordination polymer: poly[[[μ-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N]-(μ-3,3′-thiodipropionato-κ3O,O′:O)-cadmium(II)] monohydrate]
Hao, Xiao-Min
Chen, Gang
Gu, Chang-Sheng
Liu, Ji-Wei
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2014, 70 : 712 - +
[47] Poly[[aqua(4,4′-diazenediyldibenzoato-κ4O,O′:O",O′′′)cadmium(II)]: a twofold interpenetrated three-dimensional coordination polymer of PtS topology
Wang, Ru-Guo
Qiao, Qian
Tang, Tian-Di
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 : M388 - M390
[48] Synthesis and Structural Characterization of a New 1-D Lead(II) Coordination Polymer: A New Precursor for Preparation Pb3I2O2 Nano Particles Via Thermal Decomposition
Mohammad Jaafar Soltanian Fard
Hakimeh Sadat Naraghi
Journal of Chemical Crystallography, 2013, 43 : 207 - 212
[49] A new three-dimensional barium(II) coordination polymer constructed from N,N′-bis(glycinyl)-pyromellitic diimide: microwave-assisted synthesis, structure, Hirshfeld surface analysis and properties
Ding, Xin-Yu
Yu, Hai-Yan
Zhang, Hong-Tao
Wang, Xiao-Long
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2024, 80 : 648 - +
[50] A three-dimensional (3,4)-connected network of 658 topology containing hexagonal channels constructed from cadmium(II) and 5-aminoisophthalate
Tao, J
Yin, X
Jiang, YB
Huang, RB
Zheng, LS
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (09) : 1171 - 1174

← 1 2 3 4 5 →