A new self-penetrating amine-decorated microporous metal-organic framework: Crystal structure, adsorption selectivity, and luminescence properties

被引：6
作者：
Shi, Zheng-Hai [1 ]
Zhang, Li [1 ]
Yu, Hai-Yan [1 ]
机构：
[1] Nanyang Inst Technol, Sch Biochem & Chem Engn, Nanyang 473004, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 54卷
关键词：
Metal-organic framework; Self-penetrating; Sorption; Luminescence; CARBON-DIOXIDE CAPTURE; COORDINATION POLYMERS; CO2; CONSTRUCTION; SITES; MOFS; SEPARATION; SORPTION; LIGANDS; DESIGN;
D O I：
10.1016/j.inoche.2015.02.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new microporous metal-organic framework, [Cd(bpdc)(0.5)(atz)(DMF)]center dot 0.5DMF (1) (H(2)bpdc = 4,4'-biphenyldicarboxylic acid, Hatz = 3-amino-1,2,4-triazole, DMF = N,N-dimethylformamide) has been solvothermally synthesized by employing the mixed H(2)bpdc and Hatz ligands. 1 is a 3D pillared-layer framework, consisting of Cd-triazolate layer and dicarboxylate pillar, which exhibits a 6-connected (4(6)center dot 6(8)center dot 8) self-penetrating net. Because of the pore system functionalized by amino groups and open metal sites, this material shows high CO2 adsorption selectivity over H-2 and N-2. In addition, 1 exhibits blue emission at ambient temperature. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：77 / 80
页数：4
相关论文
共 37 条
[1]   Discrete metal-carboxylate self-assembled cages: Design, synthesis and applications [J].
Ahmad, Nazir ;
Chughtai, Adeel H. ;
Younus, Hussein A. ;
Verpoort, Francis .
COORDINATION CHEMISTRY REVIEWS, 2014, 280 :1-27
[2]   Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks [J].
Bae, Youn-Sang ;
Mulfort, Karen L. ;
Frost, Houston ;
Ryan, Patrick ;
Punnathanam, Sudeep ;
Broadbelt, Linda J. ;
Hupp, Joseph T. ;
Snurr, Randall Q. .
LANGMUIR, 2008, 24 (16) :8592-8598
[3]   Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification [J].
Bae, Youn-Sang ;
Farha, Omar K. ;
Hupp, Joseph T. ;
Snurr, Randall Q. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (15) :2131-2134
[4]   Mixed Linker Strategies for Organic Framework Functionalization [J].
Bunck, David N. ;
Dichtel, William R. .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (03) :818-827
[5]   Construction of Ba(II) Coordination Polymers Based on Imidazole-Based Dicarboxylate Ligands: Structural Diversity Tuned by Alcohol Solvents [J].
Cai, Song-Liang ;
Zheng, Sheng-Run ;
Wen, Zhen-Zhen ;
Fan, Jun ;
Zhang, Wei-Guang .
CRYSTAL GROWTH & DESIGN, 2012, 12 (07) :3575-3582
[6]   Synthesis, Crystal Structure, and Photoluminescence of a Series of Zinc(II) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands [J].
Chen, Shui-Sheng ;
Fan, Jian ;
Okamura, Taka-aki ;
Chen, Man-Sheng ;
Su, Zhi ;
Sun, Wei-Yin ;
Ueyama, Norikazu .
CRYSTAL GROWTH & DESIGN, 2010, 10 (02) :812-822
[7]   A novel 3D self-penetrating framework self-assembled from interweaving double-helical chains [J].
Chi, Xiao-Lin ;
Liu, Jun-Liang ;
Chen, Hai-Yan ;
Yang, Juan ;
Zhang, Hua-Yi ;
Zhang, Jin-Ling ;
Chen, Yu ;
Yang, Qi ;
Xiao, Dong-Rong .
INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 50 :101-105
[8]   Design and construction of coordination polymers with mixed-ligand synthetic strategy [J].
Du, Miao ;
Li, Cheng-Peng ;
Liu, Chun-Sen ;
Fang, Shao-Ming .
COORDINATION CHEMISTRY REVIEWS, 2013, 257 (7-8) :1282-1305
[9]   Syntheses, structures, and photoluminescent properties of a series of zinc(II)-3-amino-1,2,4-triazolate coordination polymers constructed by varying carboxylate anions [J].
Gao, JinYing ;
Wang, Ning ;
Xiong, XiaHua ;
Chen, ChuJun ;
Xie, WeiPing ;
Ran, XingRui ;
Long, Yi ;
Yue, ShanTang ;
Liu, YingLiang .
CRYSTENGCOMM, 2013, 15 (17) :3261-3270
[10]   An interpenetrated pillared-layer MOF: Synthesis, structure, sorption and magnetic properties [J].
Jia, Li-Na ;
Zhao, Yang ;
Hou, Lei ;
Cui, Lin ;
Wang, Hai-Hua ;
Wang, Yao-Yu .
JOURNAL OF SOLID STATE CHEMISTRY, 2014, 210 (01) :251-255
1234