Surface charge induced tuning of electrical properties of CVD assisted graphene and functionalized graphene sheets

We demonstrate a new approach to tune the electrical properties of graphene and functionalized graphene. Graphene was synthesized using thermal chemical vapour deposition (TCVD) method on copper foil using precursor gas acetylene and co-catalyst H-2 gas. TCVD assisted graphene was successfully transferred onto a silicon wafer. Transferred graphene sheet was then functionalized to prepare graphene oxide (GO) and reduced graphene oxide (rGO ). Different surface charge carbon nanopartides, e.g. carbon nanoparticle with net positive charge and carbon nanoparticle with net negative charge were then immobilized on transferred graphene and functionalized graphene sheets. The functionalized graphene and charge mobilized functionalized graphene were characterized by Uv-vis spectroscopy, Fourier transformed infrared spectroscopy, scanning electron microscopy, and Raman spectroscopy. After immobilization of carbon nanomaterials, the ac electrical conductivity was found to increase due to enhancement of the surface charge, electron density, and mobility. It was observed that negative surface charge immobilized graphene and functionalized graphene show higher conductivity. Thus, the electrical property of graphene and functionalized graphene can be tuned by surface modification with different surface charge carbon nanomaterials. (C) 2018 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.