Poly[bis(μ2-quinoline-3-carboxylato-κ2N:O)zinc(II)]

被引:4
作者
Hu, Sheng [1 ]
Zhang, Shu-Hua [1 ]
Zeng, Ming-Hua [1 ]
机构
[1] Guangxi Normal Univ, Sch Chem & Chem Engn, Guilin 541004, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词
D O I
10.1107/S1600536807044868
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Zn(L)2] n (HL is quinoline-3-carboxylic acid, C10H7NO2), the ZnII atom is coordinated by two N atoms from two bis-monodentate L - ligands and two O atoms from two bis-monodentate L - ligands, forming a slightly distorted tetra-hedral geometry. Each bis-monodentate ligand links two Zn atoms, constructing a two-dimensional layer parallel to the (100) plane. The layers pack together into an abab pattern. These layers are linked by π-π inter-actions [face-to-face separation 3.59 (1) Å] into a supra-molecular structure. © International Union of Crystallography 2007.
引用
收藏
页码:M2565 / U1148
页数:10
相关论文
共 8 条
[1]  
*BRUK AXS INC, 1997, SHELXTL VERS 5 10
[2]  
*BRUK AXS INC, 2001, SAINT VERS 6 45 SMAR
[3]   Supramolecular engineering of chiral and acentric 2D networks. Synthesis, structures, and second-order nonlinear optical properties of bis(nicotinato)zinc and bis{3-[2-(4-pyridyl)ethenyl]benzoato}cadmium [J].
Lin, WB ;
Evans, OR ;
Xiong, RG ;
Wang, ZY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (50) :13272-13273
[4]   trans-diaquabis(quinoline-2-carboxylato-N,O)-nickel(II)-water-ethanol (1/2/2) [J].
Odoko, M ;
Muranishi, Y ;
Okabe, N .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 :m267-m269
[5]   Aquabis(quinoline-2-carboxylato-κ2N,O)zinc(II) [J].
Okabe, N ;
Muranishi, Y .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :M244-M246
[6]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR, P38
[7]  
Sheldrick G.M., 1996, SADABS VERSION 2008
[8]   A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(I,II) units [J].
Tong, ML ;
Li, LJ ;
Mochizuki, K ;
Chang, HC ;
Chen, XM ;
Li, Y ;
Kitagawa, S .
CHEMICAL COMMUNICATIONS, 2003, (03) :428-429