Crystal orientation of β-Ga2O3 thin films formed on c-plane and a-plane sapphire substrate

被引:192
作者
Nakagomi, Shinji [1 ]
Kokubun, Yoshihiro [1 ]
机构
[1] Ishinomaki Senshu Univ, Dept Informat Technol & Elect, Fac Sci & Engn, Ishinomaki, Miyagi 9868580, Japan
关键词
Crystal structure; X-ray diffraction; Gallium compounds; Oxides; Sapphire; Semiconducting gallium compounds; MOLECULAR-BEAM EPITAXY; OXIDE; GROWTH; DEPOSITION; STABILITY; GAN;
D O I
10.1016/j.jcrysgro.2012.04.006
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
beta-Ga2O3 thin films were prepared by gallium evaporation in oxygen plasma. The crystal orientation of the beta-Ga2O3 films was studied in detail using X-ray diffraction, pole figure measurements and analysis using a crystal model. beta-Ga2O3 films formed on both the (001) c-plane and (110) a-plane of the sapphire substrate were found to be strongly ((2) over tilde 01) oriented. Six crystal types of beta-Ga2O3 are formed, rotated about the [(2) over bar 01] direction. The six directions depend on the arrangement of oxygen on the surface of the sapphire substrate. The direction of [201] of beta-Ga2O3 is vertical to the sapphire {100} planes. The arrangement of oxygen on the (001) c-plane sapphire substrate is equivalent to that formed on the ((2) over bar 01) plane of beta-Ga2O3 due to a small mismatch in the spacing between oxygen atoms. This mismatch explains why beta-Ga2O3 is ((2) over bar 01) oriented on the (001) c-plane sapphire substrate. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:12 / 18
页数:7
相关论文
共 23 条
[1]   Chemical vapour deposition and characterization of gallium oxide thin films [J].
Battiston, GA ;
Gerbasi, R ;
Porchia, M ;
Bertoncello, R ;
Caccavale, F .
THIN SOLID FILMS, 1996, 279 (1-2) :115-118
[2]   STABILITY OF SEMICONDUCTING GALLIUM OXIDE THIN-FILMS [J].
FLEISCHER, M ;
HANRIEDER, W ;
MEIXNER, H .
THIN SOLID FILMS, 1990, 190 (01) :93-102
[3]   EFFECT OF THE SENSOR STRUCTURE ON THE STABILITY OF GA(2)O(3) SENSORS FOR REDUCING GASES [J].
FLEISCHER, M ;
HOLLBAUER, L ;
MEIXNER, H .
SENSORS AND ACTUATORS B-CHEMICAL, 1994, 18 (1-3) :119-124
[4]   Uniaxial locked epitaxy of ZnO on the a face of sapphire [J].
Fons, P ;
Iwata, K ;
Yamada, A ;
Matsubara, K ;
Niki, S ;
Nakahara, K ;
Tanabe, T ;
Takasu, H .
APPLIED PHYSICS LETTERS, 2000, 77 (12) :1801-1803
[5]   Gallium oxide (Ga2O3) metal-semiconductor field-effect transistors on single-crystal β-Ga2O3 (010) substrates [J].
Higashiwaki, Masataka ;
Sasaki, Kohei ;
Kuramata, Akito ;
Masui, Takekazu ;
Yamakoshi, Shigenobu .
APPLIED PHYSICS LETTERS, 2012, 100 (01)
[6]   NEW EPITAXIAL RELATIONSHIPS OF SINGLE-CRYSTAL ZINC-OXIDE ON SAPPHIRE [J].
KASUGA, M ;
MOCHIZUKI, M ;
KOBAYASHI, K ;
SHIMIZU, A .
JAPANESE JOURNAL OF APPLIED PHYSICS, 1980, 19 (11) :2289-2290
[7]   Sol-gel prepared β-Ga2O3 thin films for ultraviolet photodetectors [J].
Kokubun, Yoshihiro ;
Miura, Kasumi ;
Endo, Fumie ;
Nakagomi, Shinji .
APPLIED PHYSICS LETTERS, 2007, 90 (03)
[8]   Investigation of the oxygen gas sensing performance of Ga2O3 thin films with different dopants [J].
Li, YX ;
Trinchi, A ;
Wlodarski, W ;
Galatsis, K ;
Kalantar-zadeh, K .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :431-434
[9]   Field-induced current modulation in epitaxial film of deep-ultraviolet transparent oxide semiconductor Ga2O3 [J].
Matsuzaki, K ;
Yanagi, H ;
Kamiya, T ;
Hiramatsu, H ;
Nomura, K ;
Hirano, M ;
Hosono, H .
APPLIED PHYSICS LETTERS, 2006, 88 (09)
[10]   GaN growth on sapphire [J].
Melton, WA ;
Pankove, JI .
JOURNAL OF CRYSTAL GROWTH, 1997, 178 (1-2) :168-173