Charge-Transfer Properties of Lateral Triphenylamine-Dithienophosphole Diads

被引：18
作者：
Chua, Chris Jansen
Ren, Yi
Baumgartner, Thomas [1 ]
机构：
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
来源：
ORGANIC LETTERS | 2012年 / 14卷 / 06期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
BUILDING-BLOCKS; SYSTEMS;
D O I：
10.1021/ol300331f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Installation of an exocyclic triphenylamine group at the phosphorus center provides access to dithienophosphole materials with lateral charge. transfer (CT) ability. The degree of CT can be significantly manipulated not only via oxidation of the P-center but also surprisingly by alkylation of the 2,6-position of the scaffold.
引用
收藏
页码：1588 / 1591
页数：4
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