Component dynamics in polyisoprene/polyvinylethylene blends well above Tg

被引:76
作者
Min, BC
Qiu, XH
Ediger, MD [1 ]
Pitsikalis, M
Hadjichristidis, N
机构
[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
[2] Univ Athens, Dept Chem, Athens 15771, Greece
关键词
D O I
10.1021/ma0018345
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
C-13 and H-2 NMR relaxation time measurements were performed on low molecular weight blends of polyisoprene (M-n = 1350 g/mol) and deuterated polyvinylethylene (1,2-polybutadiene; M-n = 2350 g/mol) in order to extract the segmental correlation times for each component. A wide range of temperatures (295-405 K) and several compositions (PI/dPVE: 100/0,70/30, 50/50, 30/70, and 0/100! were investigated. At high temperatures, dPVE dynamics are 6 times slower than PI dynamics even after considering self-concentration effects. This intrinsic mobility difference is in quantitative agreement with measurements on each chain individually as a dilute component in a common solvent, suggesting a purely intramolecular origin. The reported correlation times at various compositions fit together smoothly with those obtained by Kornfield and co-workers near T,, thus providing a unified data set for resting models. One model based on local composition fluctuations captures some qualitative features of the experimental data while failing to describe others.
引用
收藏
页码:4466 / 4475
页数:10
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