Converting rubber seed oil into hydrocarbon fuels via supported Pd-catalyst

被引:9
作者
Chen Yubao [1 ]
Hao Yajie [1 ]
Zhao Yongyan [1 ]
Zhou Liming [1 ]
Yang Shunping [1 ]
Gao Yanni [1 ]
Ma Jiangli [2 ]
Du Junchen [2 ]
Souliyathai, Dona [1 ]
Zhang Aimin [2 ]
机构
[1] Yunnan Normal Univ, China Laos Joint Lab Renewable Energy Utilizat &, Kunming 650500, Yunnan, Peoples R China
[2] Kunming Inst Precious Met, Kunming 650106, Yunnan, Peoples R China
基金
中国国家自然科学基金;
关键词
rubber tree seed oil; catalytic cracking; Pd based catalyst; hydrocarbon fuels; biofuel; renewable energy; VEGETABLE-OILS; FATTY-ACIDS; TRIGLYCERIDES; DEOXYGENATION; BIOMASS; DECARBOXYLATION; CRACKING; NICKEL; TAR;
D O I
10.25165/j.ijabe.20171006.2742
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The one-step hydrotreatment of rubber seed oil to produce hydrocarbon fuels has been carried out via supported Pd-catalyst, and analyzed emphatically some elements affected catalytic cracking process, for example, temperature, hydrogen partial pressure and dosage of catalyst, etc. Through experimental research, the author found out the appropriate catalytic cracking conditions as follows: 310 degrees C of reaction temperature, 2 MPa of hydrogen partial pressure, 15 of the ratio of oil to catalyst (m(oil)/ m(catalyst)), 100 r/min of stirring speed. Under these conditions, effective component of hydrocarbon fuels in the converted oil accounts for 99.49%, and the proportion of C-8-C-16 can reach as high as 79.61%. The converted oil was similar to petroleum-based oil in chemical composition, and can be used for future the aviation biofuels development as the source of raw material because it contains a large amount of hydrocarbon in the range of C-8-C-16.
引用
收藏
页码:201 / 209
页数:9
相关论文
共 24 条
[1]   Competitive liquid biofuels from biomass [J].
Demirbas, Ayhan .
APPLIED ENERGY, 2011, 88 (01) :17-28
[2]  
[高金森 Gao Jinsen], 2014, [中国科学. 化学, Scientia Sinica Chimica], V44, P1385
[3]   Experimental Investigations To Study the Characteristics of Rubber-Seed-Oil-Fueled Diesel Engine Supplemented with Diethyl Ether [J].
Geo, V. Edwin ;
Nagarajan, G. ;
Kamalakannan, J. ;
Nagalingalm, B. .
ENERGY & FUELS, 2009, 23 (1-2) :533-538
[4]  
[韩伟 HAN Wei], 2007, [化工进展, Chemical Industry and Engineering Progress], V26, P1395
[5]  
He M Y, 2010, TROPIC AGR SCI TECHN, V33, P36
[6]   Catalytic reaction pathways in liquid-phase deoxygenation of C18 free fatty acids [J].
Immer, Jeremy G. ;
Kelly, M. Jason ;
Lamb, H. Henry .
APPLIED CATALYSIS A-GENERAL, 2010, 375 (01) :134-139
[7]   In-chamber thermocatalytic tar cracking and syngas reforming using char-supported NiO catalyst in an updraft biomass gasifier [J].
James, Arthur M. ;
Yuan, Wenqiao ;
Boyette, Michael D. ;
Wang, Donghai ;
Kumar, Ajay .
INTERNATIONAL JOURNAL OF AGRICULTURAL AND BIOLOGICAL ENGINEERING, 2014, 7 (06) :91-97
[8]   Hydrocarbons for diesel fuel via decarboxylation of vegetable oils [J].
Kubicková, I ;
Snåre, M ;
Eränen, K ;
Mäki-Arvela, P ;
Murzin, DY .
CATALYSIS TODAY, 2005, 106 (1-4) :197-200
[9]   Utilization of Triglycerides and Related Feedstocks for Production of Clean Hydrocarbon Fuels and Petrochemicals: A Review [J].
Kubickova, Iva ;
Kubicka, David .
WASTE AND BIOMASS VALORIZATION, 2010, 1 (03) :293-308
[10]  
Li ChangZhu Li ChangZhu, 2012, Journal of China Agricultural University, V17, P165