Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media

被引：19

作者：

Cassani, Julia ^{[1
]}

Luna, Hector ^{[1
]}

Navarro, Arturo ^{[2
]}

Castillo, Edmundo ^{[3
]}

机构：

[1] Univ Autonoma Metropolitana, Dept Sistemas Biol, Unidad Xochimilco, Ciudad Mexico 04960, Mexico

[2] Univ Nacl Autonoma Mexico, Fac Quim, Dept Alimentos & Biotecnol, Ciudad Mexico 04510, Mexico

[3] Univ Nacl Autonoma Mexico, Inst Biotecnol, Dept Ingn Celular & Biocatalisis, Cuernavaca 62271, Morelos, Mexico

来源：

ELECTRONIC JOURNAL OF BIOTECHNOLOGY | 2007年 / 10卷 / 04期

关键词：

CAL-B; electronic effects; esterification; lipase; phenylpropanoid;

D O I：

10.2225/vol10-issue4-fulltext-3

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The esterification of phenylpropanoid and hydrophenylpropanoid acids, catalyzed by candida antarctica lipase B (CAL-B), with several alcohols has demonstrated that the substitution pattern on the aromatic ring has a very significant influence on the reactivity of the carboxyl group due, mainly, to electronic effects, when compared to the unsaturated acids with the hydrogenated acids. It is also clear that in the saturated acids there still remain some unclear effects related to the aromatic substituents.

引用

页码：508 / 513

页数：6

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