2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion

被引：14

作者：

Puttreddy, Rakesh ^{[1
]}

Beyeh, Ngong Kodiah ^{[2
]}

Kalenius, Elina ^{[1
]}

Ras, Robin H. A. ^{[2
]}

Rissanen, Kari ^{[1
]}

机构：

[1] Univ Jyvaskyla, Dept Chem, Nanosci Ctr, POB 35, FI-40014 Jyvaskyla, Finland

[2] Aalto Univ, Dept Appl Phys, Puumiehenkuja 2, Espoo 02150, Finland

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 52期

基金：

芬兰科学院;

关键词：

HOST-GUEST CHEMISTRY; ETHYL RESORCINARENE; SOLID-STATE; RECOGNITION; COMPLEXES; MECHANISMS; ALCOHOLS; SOLVENTS; CHOLINE; WATER;

D O I：

10.1039/c6cc03289c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)(2+) inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1 center dot H2O center dot MeOH](2)(2-) with a cavity volume of 165 angstrom(3) and (TDAC)(2+) as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50 : 50 ratio in the crystal lattice.

引用

页码：8115 / 8118

页数：4

共 3 条

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