Amination of NCD Films for Possible Application in Biosensing

被引:23
作者
Artemenko, Anna [1 ]
Kozak, Halyna [1 ]
Biederman, Hynek [2 ]
Choukourov, Andrei [2 ]
Kromka, Alexander [3 ]
机构
[1] ASCR, Inst Phys, Vvi, Prague 16200 6, Czech Republic
[2] Charles Univ Prague, Fac Math & Phys, Dept Macromol Phys, Prague 18100 8, Czech Republic
[3] Acad Sci Czech Republ, Inst Phys, Vvi, CR-16200 Prague 6, Czech Republic
关键词
amination; nanocrystalline diamond; surface conductivity; surface functionalization; XPS; PLASMA-POLYMER-FILMS; DIAMOND SURFACES; OXYGEN; DNA; IMMOBILIZATION; SIO2; FETS;
D O I
10.1002/ppap.201400151
中图分类号
O59 [应用物理学];
学科分类号
摘要
Nanocrystalline diamond (NCD) films may be used in biosensing after modification of their surfaces with active functional groups. Here, surface functionalization of O- and H-NCD films with amine groups was made by 2 plasma-based processes: a) RF plasma treatment in ammonia, b) the deposition of thin amine-containing plasma polymer via RF magnetron sputtering of nylon target in Ar/N-2 mixture. Amination of the NCD films by plasma treatment in NH3 caused an attachment of 1% of primary amines but destroyed the surface conductivity of H-NCD films. The 5% concentration of -NH2 was detected on the NCD covered with the plasma polymer. Moreover, the surface conductivity of H-NCD films reached 10(-7) S.
引用
收藏
页码:336 / 346
页数:11
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