A new family of pyrazolyl-based anionic bidentate ligands and crystal structure of bis(N-phenyl-2-pyrazolyl-1-carboximidothioato)copper(II)

被引：12

作者：

Sadr, MH ^{[1
]}

Jalili, AR

Razmi, H

Ng, SW

机构：

[1] Azarbaijan Univ Tarbiat Moallem, Dept Chem, Tabriz, Iran

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 08期

关键词：

pyrazolyl-based ligands; polypyrazolylborate; copper complexes; model compounds;

D O I：

10.1016/j.jorganchem.2005.01.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new N,S-donor bidentate pyrazolyl-based ligands abbreviated as [PhNCSPz](-), 1, [PhNCSPz(Me2)](-), 2, and [PhNCSPz(Ph2)](-), 3, have been synthesized in THF by direct mixing of phenylisothiocyanide with suspension of appropriate sodium-pyrazolate salts and characterized by the common spectroscopic and analytical methods. The Cu(II) complexes of these anionic chelate ligands have been characterized and the crystal structure of Cu(PhNCSPz)(2), 4, has been determined. The space group of complex is P2(1)c, with a = 5.9313(3), b = 21.206(1) angstrom, c = 8.0667(4) angstrom, beta = 103.822(1)degrees. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：2128 / 2132

页数：5

共 12 条

[1] Synthesis, structure, and properties of {N,N′-bis[2-(1-pyrazolyl)ethyl]pyridine-2,6-dicarboxamido}copper(II)
Chavez, FA
Olmstead, MM
Mascharak, PK
INORGANICA CHIMICA ACTA, 1998, 269 (02) : 269 - 273
[2] A new class of biomimetically relevant 'Scorpionate' ligands -: III.: The bis(pyrazolyl)methane(phen-2′-ol)s:: synthesis and structural characterization of mono and dinuclear copper(II) complexes
Higgs, TC
Ji, D
Czernuscewicz, RS
Carrano, CJ
INORGANICA CHIMICA ACTA, 1998, 273 (1-2) : 14 - 23
[3] Synthesis, spectroscopic, magnetic and EPR studies and crystal structure of di-μ-(N-phenyl-N-methoxy-2-pyridinamine)bis[(NN) copper(II)]perchlorate, NN=2,2′-bipyridyl or 1,10-phenanthroline
Seco, JM
Amador, U
Garmendia, MJG
INORGANICA CHIMICA ACTA, 2000, 303 (02) : 256 - 264
[4] An alternating copper(II) chain with bridging oxamidato and nitrito ligands:: crystal structure and magnetic properties of [Cu(NO2)2CuL]n (L = N,N′-bis(2-methyl-2-aminopropyl) oxamide)
Costes, JP
Dahan, F
Laurent, JP
Drillon, M
INORGANICA CHIMICA ACTA, 1999, 294 (01) : 8 - 13
[5] Crystal structure and Hirshfeld surface analysis of di-μ-chlorido-bis[(acetonitrile-κN)chlorido(ethyl 5-methyl-1H-pyrazole-3-carboxylate-κ2N2,O)-copper(II)]
Vynohradov, Oleksand S.
Pavlenko, Vadim A.
Kucheriv, Olesia, I
Golenya, Irina A.
Petlovanyi, Denys
Shova, Sergiu
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 1153 - +
[6] Ligand behaviour of a bis-pyridazinecarboxamide copper(II) complex towards nickel(II) beta-diketonates. X-ray crystal structure of Cu(bpdpn)Ni(hfacac)(2) (H(2)bpdpn=N,N'-bis(3'-pyridazinecarboxamide)-1,3-propane, Hhfacac=hexafluoroacetylacetone), a heterometallic bridged complex
Miah, MAA
Phillips, DJ
Rae, AD
INORGANICA CHIMICA ACTA, 1996, 245 (02) : 231 - 235
[7] Luminescent tetranuclear copper(I) clusters containing tetradentate N,S Schiff base ligands. X-ray crystal structure of Cu(4)L(2) (L=N,N'-(2,2'-diphenyl)-bis(1,3-diphenyl-4-iminomethyl-5-thiopyrazole))
Rasmussen, JC
Toftlund, H
Nivorzhkin, AN
Bourassa, J
Ford, PC
INORGANICA CHIMICA ACTA, 1996, 251 (1-2) : 291 - 298
[8] Three dinuclear copper(II) carboxylates with the paddle-wheel cage structure as intermediates in copper(II) catalyzed oxidations of carboxylic acids. X-ray crystal structures of [tetrakis(diphenylacetato-mu-O,O')bis(acetonitrile-N)dicopper(II)] tetrakis(acetonitrile) [tetrakis(diphenylacetato-mu-O,O')bis(acetone-O)dicopper(II)] and [tetrakis(1-phenyl-1-carboxylato-mu-O,O'-cyclopentane)-bis(ethanol-O)dicopper(II)] bis(ethanol)
Agterberg, FPW
Kluit, HAJP
Driessen, WL
Reedijk, J
Oevering, H
Buijs, W
Veldman, N
Lakin, MT
Spek, AL
INORGANICA CHIMICA ACTA, 1998, 267 (02) : 183 - 192
[9] New dinuclear copper complexes incorporating bis(imidazolyl) based ligands and bidentate-monodentate oxalate bridges. Crystal structure and magnetic properties of [Cu2(BIM)2(C2O4)2]•4H2O and [Cu2(BIK)2(C2O4)2] (BIM = bis(2-imidazolyl)methane), BIK = bis(2-imidazolyl)ketone). Exploring magneto-structural correlations
Escriva, Emilio
Folgado, Jose-Vicente
Minguez Espallargas, Guillermo
Soto, Lucia
Sancho, Amparo
Perello, Lourdes
Ortiz, Rosa
POLYHEDRON, 2016, 112 : 137 - 144
[10] X-RAY CRYSTAL-STRUCTURE OF CU-2(MEDPCO-2H)CL-2, (MEDPCO=N,N'-BIS(2-N,N-DIMETHYLAMINOETHYL)PYRIDINE-2,6-DICARBOXAMIDE 1-OXIDE - COPPER(II) COMPLEXES OF A DEPROTONATED BINUCLEATING PYRIDINE N-OXIDE LIGAND
ANTOLOVICH, M
PHILLIPS, DJ
RAE, AD
INORGANICA CHIMICA ACTA, 1995, 230 (1-2) : 139 - 144

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