Synthesis, Crystal Structure, Magnetic, Thermal and Fluorescent Properties of [Co(H2O)4(nia)2](suc)•(H2suc)

被引：4

作者：

Demir, Selcuk ^{[1
]}

Yilmaz, Veysel T. ^{[2
]}

Mrozinski, Jerzy ^{[3
]}

Lis, Tadeusz ^{[3
]}

Holynska, Malgorzata ^{[3
]}

机构：

[1] Rize Univ, Dept Chem, Fac Arts & Sci, TR-53100 Rize, Turkey

[2] Uludag Univ, Fac Arts & Sci, Dept Chem, TR-16100 Bursa, Turkey

[3] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2010年 / 65卷 / 06期

关键词：

Succinate Complexes; Nicotinamide; Crystal Structure; Thermal Analysis; Magnetic Interaction; COORDINATION POLYMERS; ALIPHATIC DICARBOXYLATES; SUCCINIC ACID; ARCHITECTURES; NICOTINAMIDE; COBALT(II); COMPLEXES; LIGAND; PHEN=1,10-PHENANTHROLINE; PHENANTHROLINE;

D O I：

10.1515/znb-2010-0605

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new cobalt(II) complex, [Co(H2O)(4)(nia)(2)](suc)center dot(H(2)suc) [nicotinamide = nia, succinate = suc(2-)], has been synthesized and characterized by elemental analysis, IR. TG-DTA and single-crystal X-ray diffraction. It contains [Co(H2O)(4)(nia)(2)](2+) complex cations, uncoordinated suc(2-) anios and H(2)suc species. In the complex cation the cobalt(H) ion is coordinated by four aqua and two nia ligands in a distorted octahedral geometry. The suc(2-) dianion acts as a counter-ion, while H(2)suc is present as a molecule of solvation. A three-dimensional network is formed by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. The title complex exhibits luminescence in the solid state at room temperature. The magnetism of the complex was studied over the temperature range 1.8 - 300 K.

引用

页码：695 / 700

页数：6

共 32 条

[1]

AZIZOV TA, 1991, ZH NEORG KHIM+, V36, P1722

[2] Crystal structures of mixed ligand complexes containing saccharinate and nicotinamide:: [Cu(saccharinato)2 (nicotinamide) (H2O)]•(H2O) and [M(nicotinamide)2 (H2O)4]•(saccharinate)2 (M = Ni2+, Co2+) [J].

Çakir, S ;

Bulut, I ;

Aoki, K .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (11) :875-884

[3] Crystal structure and vibrational behaviour of tetraaqua-di(nicotinamide)M(II)-saccharinates, with M(II) = Co, Ni, Zn [J].

Castellano, EE ;

Piro, OE ;

Parajón-Costa, BS ;

Baran, EJ .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2002, 57 (06) :657-660

[4] Synthesis, crystal structure and magnetic properties of two-dimensional malonato-bridged cobalt(II) and nickel(II) compounds [J].

Delgado, FS ;

Hernández-Molina, M ;

Sanchi, J ;

Ruiz-Pérez, C ;

Rodríguez-Martín, Y ;

López, T ;

Lloret, F ;

Julve, M .

CRYSTENGCOMM, 2004, 6 :106-111

[5] Metal(II) Nicotinamide Complexes Containing Succinato, Succinate and Succinic Acid: Synthesis, Crystal Structures, Magnetic, Thermal, Antimicrobial and Fluorescent Properties [J].

Demir, Selcuk ;

Yilmaz, Veysel T. ;

Sariboga, Bahtiyar ;

Buyukgungor, Orhan ;

Mrozinski, Jerzy .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2010, 20 (02) :220-228

[6] One-Dimensional Cobalt(II) and Zinc(II) Succinato Coordination Polymers with Nicotinamide: Synthesis, Structural, Spectroscopic, Fluorescent and Thermal Properties [J].

Demir, Selcuk ;

Yilmaz, Veysel T. ;

Yilmaz, Fatih ;

Buyukgungor, Orhan .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2009, 19 (03) :342-347

[7] Toward the recognition of enolates/dicarboxylates:: Syntheses and X-ray crystal structures of supramolecular architectures of Zn(II)/Cd(II) using 2,2′-biimidazole [J].

Ghosh, AK ;

Jana, AD ;

Ghoshal, D ;

Mostafa, G ;

Chaudhuri, NR .

CRYSTAL GROWTH & DESIGN, 2006, 6 (03) :701-707

[8] Cobalt and nickel oxide architectures in metal carboxylate frameworks:: From coordination polymers to 3D inorganic skeletons [J].

Guillou, Nathalie ;

Livage, Carine ;

Ferey, Gerard .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (24) :4963-4978

[9] Hydrothermal synthesis, structural characterization, magnetic and photoelectric properties of two cobalt(II) coordination polymers [J].

Jin, Jing ;

Niu, Shu Yun ;

Di Yang, Guang ;

Ye, Ling .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (14) :2350-2354

[10] Synthesis, spectral and crystallographic characterization of manganese(II) coordination polymers based on aliphatic dicarboxylate and flexible bis(imidazolyl) derivatives [J].

Jin, Shouwen ;

Chen, Wanzhi .

INORGANICA CHIMICA ACTA, 2007, 360 (12) :3756-3764

← 1 2 3 4 →