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Efficient photocatalytic degradation of toxic dyes using nanostructured TiO2/polyaniline nanocomposite
被引:35
|作者:
Gnanasekaran, Lalitha
[1
]
Hemamalini, R.
[1
]
Naushad, Mu
[2
]
机构:
[1] Queen Marys Coll, Dept Phys, Madras 600004, Tamil Nadu, India
[2] King Saud Univ, Coll Sci, Dept Chem, Bldg 5, Riyadh, Saudi Arabia
关键词:
Metal oxide;
Polyaniline;
Conducting polymer;
Methyl orange;
Photocatalyst;
VISIBLE-LIGHT;
CONJUGATED POLYMERS;
METHYLENE-BLUE;
MODIFIED TIO2;
ADSORPTION;
MECHANISM;
NANOPARTICLES;
PERFORMANCE;
COMPOSITE;
REMOVAL;
D O I:
10.5004/dwt.2018.21967
中图分类号:
TQ [化学工业];
学科分类号:
0817 ;
摘要:
In this study, the synergistic effect between polyaniline and TiO2 nanoparticles make favorable accomplishment of aqueous methyl orange (MO) and methylene blue (MB) dyes. Before the degradation reaction, two-step methods were executed to prepare nanocomposite (TiO2/polyaniline) systems. Apart from synthesis, characteristics of the materials were perceived via x-ray diffraction, transmission electron microscopy, FOURIER transform infra red and UV-Vis techniques. The characteristic outcomes described the presence of polyaniline which suggestively impacts the size and crystallinity of TiO2 and additionally, initiate pi-pi* transition under visible light illumination. The pi-pi* transition was excited to generate more electrons and holes in the nanocomposites and it helps to achieve visible light degradation of MO and MB.
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页码:322 / 328
页数:7
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