Efficient photocatalytic degradation of toxic dyes using nanostructured TiO2/polyaniline nanocomposite

被引:35
作者
Gnanasekaran, Lalitha [1 ]
Hemamalini, R. [1 ]
Naushad, Mu [2 ]
机构
[1] Queen Marys Coll, Dept Phys, Madras 600004, Tamil Nadu, India
[2] King Saud Univ, Coll Sci, Dept Chem, Bldg 5, Riyadh, Saudi Arabia
关键词
Metal oxide; Polyaniline; Conducting polymer; Methyl orange; Photocatalyst; VISIBLE-LIGHT; CONJUGATED POLYMERS; METHYLENE-BLUE; MODIFIED TIO2; ADSORPTION; MECHANISM; NANOPARTICLES; PERFORMANCE; COMPOSITE; REMOVAL;
D O I
10.5004/dwt.2018.21967
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, the synergistic effect between polyaniline and TiO2 nanoparticles make favorable accomplishment of aqueous methyl orange (MO) and methylene blue (MB) dyes. Before the degradation reaction, two-step methods were executed to prepare nanocomposite (TiO2/polyaniline) systems. Apart from synthesis, characteristics of the materials were perceived via x-ray diffraction, transmission electron microscopy, FOURIER transform infra red and UV-Vis techniques. The characteristic outcomes described the presence of polyaniline which suggestively impacts the size and crystallinity of TiO2 and additionally, initiate pi-pi* transition under visible light illumination. The pi-pi* transition was excited to generate more electrons and holes in the nanocomposites and it helps to achieve visible light degradation of MO and MB.
引用
收藏
页码:322 / 328
页数:7
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