Initial formation of corrosion products on pure zinc in simulated body fluid

被引:101
作者
Liu, Lijun [1 ]
Meng, Yao [1 ]
Dong, Chaofang [1 ,2 ]
Yan, Yu [2 ]
Volinsky, Alex A. [3 ]
Wang, Lu-Ning [1 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
[2] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Beijing 100083, Peoples R China
[3] Univ S Florida, Dept Mech Engn, Tampa, FL 33620 USA
基金
中国国家自然科学基金;
关键词
Zinc; Stent; Corrosion; Simulated body fluid; IN-VITRO DEGRADATION; ZN-BASED ALLOYS; PHOSPHATE BUFFERED SALINE; CALCIUM-PHOSPHATE; MICROGALVANIC CORROSION; BIODEGRADABLE METALS; MAGNESIUM ALLOY; BINARY-ALLOYS; BONE FIXATION; ELEMENTS MG;
D O I
10.1016/j.jmst.2018.05.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Zinc was recently suggested to be a potential candidate material for degradable coronary artery stent. The corrosion behavior of pure zinc exposed to r-SBF up to 336 h was investigated by electrochemical measurements and immersion tests. The morphology and chemical composites of the corrosion products were investigated by scanning electron microscope, grazing-incidence X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transform infrared spectrometer. The results demonstrate that the initial corrosion products on the pure zinc mainly consist of zinc oxide/hydroxide and zinc/calcium phosphate compounds. The pure Zn encounters uniform corrosion with an estimated corrosion rate of 0.02-0.07 mmy(-1) during the immersion, which suggests the suitability of pure Zn for biomedical applications. (C) 2018 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
引用
收藏
页码:2271 / 2282
页数:12
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