Reaction of zinc enolates derived from 1-aryl-2,2-dibromoalkan-1-ones with tetramethyl 2,2′-(1,4-phenylenedimethylidene)dimalonate, dimethyl 3,3′-(1,4-phenylene)bis(2-cyanoacrylate), and 2,2′-(1,4-phenylenedimethylidene)-bis(malononitrile)

被引:0
作者
Shchepin, V. V. [1 ]
Uzun, D. V. [1 ]
Stepanyan, Yu. G. [1 ]
Silaichev, P. S. [1 ]
Vakhrin, M. I. [1 ]
机构
[1] Perm State Univ, Perm 614990, Russia
基金
俄罗斯基础研究基金会;
关键词
Cyclopropane; Tetramethyl; Dicarboxylate; Malononitrile; Cyclopropane Ring;
D O I
10.1134/S1070428007070093
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Zinc enolates derived from 1-aryl-2,2-dibromoalkanones reacted with tetramethyl 2,2'-(1,4-phenylenedimethylidene)dimalonate, dimethyl 3,3'-(1,4-phenylene)bis(2-cyanoacrylate), and 2,2'-(1,4-phenylenedimethylidene)bis(malononitrile) to give, respectively, tetramethyl 3,3'-(1,4-phenylene)bis(2-alkyl-2-aroylcyclopropane-1,1-dicarboxylates), dimethyl 3,3'-(1,4-phenylene)bis(2-alkyl-2-aroyl-1-cyanocyclopropane-1-carboxylates), and 3,3'-(1,4-phenylene)bis(2-alkyl-2-aroylcyclopropane-1,1-dicarbonitriles) as a single stereoisomer.
引用
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页码:995 / 997
页数:3
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