The determination of the integral enthalpies of mixing of liquid Au-In-Sn alloys and the enthalpy of formation of the Au4In3Sn3 compound

被引:2
作者
Watson, A. [1 ]
Borzone, G. [2 ]
Parodi, N. [2 ]
Cacciamani, G. [2 ]
机构
[1] Univ Leeds, Inst Mat Res, Sch Proc Environm & Mat Engn, Leeds, W Yorkshire, England
[2] Univ Genoa, Dept Chem & Ind Chem, I-16146 Genoa, Italy
基金
英国工程与自然科学研究理事会;
关键词
High temperature calorimetry; Alloy thermochemistry; Enthalpy of formation; Enthalpy of mixing; Lead-free solders;
D O I
10.1016/j.tca.2010.06.018
中图分类号
O414.1 [热力学];
学科分类号
摘要
With a view to modelling the Au-In-Sn alloy system, the enthalpies of mixing of liquid Au-In-Sn alloys have been measured as a function of Au content by drop calorimetry at 609 degrees C for constant In:Sn ratios of 1:1, 1:3 and 3:1. For each of the three sections studied, the enthalpies of mixing were exothermic. In addition, the enthalpy of formation of the ternary Au4In3Sn3 at 298 K was measured both by direct-reaction calorimetry and by tin-solution calorimetry. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:24 / 31
页数:8
相关论文
共 11 条
[1]   Phase equilibria in the Au-In-Sn ternary system [J].
Borzone, G. ;
Parodi, N. ;
Cacciamani, G. ;
Watson, A. .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2009, 33 (01) :17-22
[2]   Thermodynamic modelling and assessment of the Au-In-Sn system [J].
Cacciamani, G. ;
Borzone, G. ;
Watson, A. .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2009, 33 (01) :100-108
[3]   ON A SIMPLE HIGH-TEMPERATURE DIRECT REACTION CALORIMETER [J].
CACCIAMANI, G ;
BORZONE, G ;
FERRO, R .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 220 (1-2) :106-110
[4]  
Coombs C.F., 2001, PRINTED CIRCUITS HDB, V5th, p29.4
[5]   SGTE DATA FOR PURE ELEMENTS [J].
DINSDALE, AT .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1991, 15 (04) :317-425
[7]   The development of the COST 531 lead-free solders thermodynamic database [J].
Kroupa, A. ;
Dinsdale, A. T. ;
Watson, A. ;
Vrestal, J. ;
Vizdal, J. ;
Zemanova, A. .
JOM, 2007, 59 (07) :20-25
[8]   Enthalpies of mixing of metallic systems relevant for lead-free soldering: Ag-Pd and Ag-Pd-Sn [J].
Luef, C ;
Paul, A ;
Flandorfer, H ;
Kodentsov, A ;
Ipser, H .
JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 391 (1-2) :67-76
[9]   ENTHALPIES OF FORMATION OF SOLID NI-CR AND NI-V ALLOYS BY DIRECT REACTION CALORIMETRY [J].
WATSON, A ;
HAYES, FH .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 220 (1-2) :94-100
[10]  
YASSIN A, 2000, J ALLOYS COMPD, V307