Critical analysis of the isoconversional methods for evaluating the activation energy. I. Theoretical background

被引：81
作者：
Budrugeac, P
Homentcovschi, D
Segal, E
机构：
[1] ICPE, Res & Dev Inst Elect Engn, Bucharest 74204, Romania
[2] Romanian Acad, Inst Appl Math, Bucharest 70700, Romania
[3] Univ Bucharest, Fac Chem, Dept Phys Chem, Bucharest, Romania
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2000年 / 63卷 / 02期
关键词：
isoconversional methods; kinetics;
D O I：
10.1023/A:1010148611036
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
It is demonstrated that, if the activation energy depends on the degree of conversion, its values obtained by isoconversional differential and integral methods are different.
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页码：457 / 463
页数：7
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