The Combination of Relay and Cooperative Catalysis with a Gold/Palladium/Bronsted Acid Ternary System for the Cascade Hydroamination/Allylic Alkylation Reaction

被引：58
|
作者：
Wu, Hua [1 ,2 ]
He, Yu-Ping [1 ,2 ]
Gong, Liu-Zhu [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 06期
关键词：
allylic alkylation; Bronsted acids; cooperative catalysis; hydroamination; metal; organocatalyst ternary system; pyrrolidine derivatives; relay catalysis; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; BRONSTED ACID; HIGHLY EFFICIENT; TRANSITION-METAL; ASYMMETRIC HYDROGENATION; ALLYLIC ALKYLATION; TANDEM SYNTHESIS; GOLD; PALLADIUM; ALDEHYDES;
D O I：
10.1002/adsc.201100922
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The combination of relay and cooperative catalysis with a gold/palladium/Br circle divide nsted acid ternary system renders a cascade hydroamination/allylic alkylation reaction to provide an unprecedented entry to pyrrolidine derivatives in high yields.
引用
收藏
页码：975 / 980
页数：6
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