Fabrication of conducting polyaniline composite film using honeycomb ordered sulfonated polysulfone film as template

被引：21

作者：

Lu, Yan ^{[2
]}

Wang, Li ^{[1
]}

Zhao, Baohui ^{[3
]}

Xiao, Guangsen ^{[1
]}

Ren, Yi ^{[1
]}

Wang, Xudong ^{[1
]}

Li, Chenxi ^{[1
]}

机构：

[1] Nankai Univ, Minist Educ, Inst Polymer Chem, Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China

[2] Tianjin Univ Technol, Minist Educ, Inst Mat Phys, Key Lab Display Mat & Photoelect Devices, Tianjin 300191, Peoples R China

[3] CNPC Res Inst Engn Technol, Tianjin 300451, Peoples R China

来源：

THIN SOLID FILMS | 2008年 / 516卷 / 18期

关键词：

composite film; sulfonated polysulfone; polyaniline; honeycomb structure; conductivity;

D O I：

10.1016/j.tsf.2007.12.138

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Sulfonated polysulfones (SPSF) with different sulfonation degrees were prepared by reaction of polysulfone with chlorosulfonic acid. The honeycomb films were fabricated by the breath figure method from freshly prepared SPSF/chlorofonn solutions. Furthen-nore, using the ordered porous SPSF films as template, honeycomb polyaniline (PANI) composite films were prepared by a simple one-step chemical oxidation polymerization of aniline. The surface morphology and conductivity of the PANVSPSF composite film were characterized by environmental scanning electron microscopy and four-probe technique, respectively. The results indicate that the SPSF honeycomb ordered film played the role as template in controlling the morphology of the PANI/SPSF composite film with the porous and electrically conductive surface. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：6365 / 6370

页数：6

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