SYNTHESIS OF FUNCTIONALIZED 2,3,4,5-TETRAPHENYLSILOLE DERIVATIVES THROUGH HYDROSILYLATION AND THEIR CRYSTAL STRUCTURES

被引：2

作者：

Zhang, Yunsheng ^{[1
,2
]}

Li, Shuhong ^{[3
]}

Wang, Rui ^{[1
,2
]}

Chen, Limin ^{[1
]}

Xu, Caihong ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China

[3] Beijing Technol & Business Univ, Sch Chem & Environm Engn, Beijing, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2012年 / 42卷 / 15期

基金：

美国国家科学基金会;

关键词：

Aggregation-induced emission; functionalized siloles; hydrosilylation; AGGREGATION-INDUCED EMISSION; TURN-ON DETECTION; SOLID-STATE; SILOLE; PHOTOLUMINESCENCE; HEXAPHENYLSILOLE; LUMINESCENCE; SENSORS; CORE;

D O I：

10.1080/00397911.2011.555049

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of new functionalized 2,3,4,5-tetraphenylsiloles were successfully synthesized in good yields by hydrosilylation reaction of 1-methyl-2,3,4,5-tetraphenyl-1H-silole with p-ethynyl benzene derivatives. This synthesis provides a convenient method of introducing reactive electron-withdrawing or electro-donating groups into siloles. All new siloles show aggregation-induced emission (AIE) effects.

引用

页码：2171 / 2180

页数：10

共 50 条

[1] NMR study of 1-hydro-2,3,4,5-tetraphenylsilole derivatives
Troitski, NA
Tandura, SN
Kolesnikov, SP
Choi, SB
Boudjouk, P
MAIN GROUP METAL CHEMISTRY, 2001, 24 (01): : 1 - 4
[2] Comparative study of the dicyanovinyl-functionalized 1,1-dimethyl-2,3,4,5-tetraphenylsilole derivatives on their structures, properties, and applications in thiol detection
Mei, Ju
Sun, Jing Zhi
Qin, Anjun
Tang, Ben Zhong
DYES AND PIGMENTS, 2017, 141 : 366 - 378
[3] Chloroplatinic acid-catalyzed hydrosilylation of acetylenes with 1-hydro, 1-methyl-(2,3,4,5-tetraphenylsilole).
Urbas, SA
Zakharov, LN
Trogler, WC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U989 - U989
[4] 13C NMR study of 2,3,4,5-tetraphenylsilole dilithium salt
S. N. Tandura
N. A. Troitskii
S. P. Kolesnikov
K. S. Nosov
M. P. Egorov
Russian Chemical Bulletin, 1999, 48 : 214 - 217
[5] 13C NMR study of 2,3,4,5-tetraphenylsilole dilithium salt
Tandura, SN
Troitskii, NA
Kolesnikov, SP
Nosov, KS
Egorov, MP
RUSSIAN CHEMICAL BULLETIN, 1999, 48 (01) : 214 - 217
[6] Electroluminescent properties of a novel σ*-π* conjugated polymer, poly[1,1-(2,3,4,5-tetraphenylsilole)]
Xu, YH
Fujino, T
Naito, H
Dohmaru, T
Oka, K
Sohn, H
West, R
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1999, 38 (12A): : 6915 - 6918
[7] Reactions of 1,1-dichloro-2,3,4,5-tetraphenylsilole with water and alcohols.
Toulokhonova, I
Zhao, RP
Kozee, M
West, R
MAIN GROUP METAL CHEMISTRY, 2001, 24 (10): : 737 - 744
[8] Photoluminescence spectral reliance on aggregation order of 1,1-bis(2′-thienyl)-2,3,4,5-tetraphenylsilole
Chen, JW
Xu, B
Yang, KX
Cao, Y
Sung, HHY
Williams, ID
Tang, BZ
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (36): : 17086 - 17093
[9] 1,1-Dimethyl-2,3,4,5-tetraphenylsilole as a Molecular Rotor Probe to Investigate the Microviscosity of Imidazolium Ionic Liquids
Scalise, Regina E.
Caradonna, Peter A.
Tracy, Henry J.
Mullin, Jerome L.
Keirstead, Amy E.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2014, 24 (02) : 431 - 441
[10] 1,1-Dimethyl-2,3,4,5-tetraphenylsilole as a Molecular Rotor Probe to Investigate the Microviscosity of Imidazolium Ionic Liquids
Regina E. Scalise
Peter A. Caradonna
Henry J. Tracy
Jerome L. Mullin
Amy E. Keirstead
Journal of Inorganic and Organometallic Polymers and Materials, 2014, 24 : 431 - 441

← 1 2 3 4 5 →