A Porphyrin-Fullerene Dyad with a Supramolecular "Double-Cable" Structure as a Novel Electron Acceptor for Bulk Heterojunction Polymer Solar Cells

被引：83
作者：
Wang, Chien-Lung [1 ]
Zhang, Wen-Bin [1 ]
Van Horn, Ryan M. [1 ]
Tu, Yingfeng [1 ]
Gong, Xiong [1 ]
Cheng, Stephen Z. D. [1 ]
Sun, Yanming [2 ]
Tong, Minghong [2 ]
Seo, Junghwa [2 ]
Hsu, Ben B. Y. [2 ]
Heeger, Alan J. [2 ]
机构：
[1] Univ Akron, Coll Polymer Sci & Polymer Engn, Akron, OH 44325 USA
[2] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
来源：
ADVANCED MATERIALS | 2011年 / 23卷 / 26期
基金：
美国国家科学基金会;
关键词：
ENERGY-CONVERSION EFFICIENCY; PENDANT FULLERENES; ORGANIC SEMICONDUCTORS; PHOTOVOLTAIC DEVICES; CONJUGATED POLYMER; DESIGN RULES; POLYTHIOPHENE; DONORS;
D O I：
10.1002/adma.201100399
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
With a supramolecular "double-cable" structure in the solid state, a light harvesting porphyrin-fullerene dyad is demonstrated to be a promising candidate for new electron acceptors in high-performance bulk heterojunction (BHJ) polymer solar cells (PSCs). It has long-lived mobile carriers, a high short circuit current, and a large open circuit voltage.
引用
收藏
页码：2951 / +
页数：7
相关论文
共 34 条
  • [1] n-Type Organic Semiconductors in Organic Electronics
    Anthony, John E.
    Facchetti, Antonio
    Heeney, Martin
    Marder, Seth R.
    Zhan, Xiaowei
    [J]. ADVANCED MATERIALS, 2010, 22 (34) : 3876 - 3892
  • [2] Benincori T., 1996, ANGEW CHEM, V108, P718
  • [3] Polymer-Fullerene Bulk-Heterojunction Solar Cells
    Brabec, Christoph J.
    Gowrisanker, Srinivas
    Halls, Jonathan J. M.
    Laird, Darin
    Jia, Shijun
    Williams, Shawn P.
    [J]. ADVANCED MATERIALS, 2010, 22 (34) : 3839 - 3856
  • [4] Organic photovoltaics: technology and market
    Brabec, CJ
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 83 (2-3) : 273 - 292
  • [5] Strain and Huckel Aromaticity: Driving Forces for a Promising New Generation of Electron Acceptors in Organic Electronics
    Brunetti, F. G.
    Gong, X.
    Tong, M.
    Heeger, A. J.
    Wudl, Fred
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (03) : 532 - 536
  • [6] Polymer solar cells: Recent development and possible routes for improvement in the performance
    Cai, Wanzhu
    Gong, Xiong
    Cao, Yong
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (02) : 114 - 127
  • [7] A soluble donor-acceptor double-cable polymer: Polythiophene with pendant fullerenes
    Cravino, A
    Zerza, G
    Maggini, M
    Bucella, S
    Svensson, M
    Andersson, MR
    Neugebauer, H
    Brabec, CJ
    Sariciftci, NS
    [J]. MONATSHEFTE FUR CHEMIE, 2003, 134 (04): : 519 - 527
  • [8] Double-cable polymers for fullerene based organic optoelectronic applications
    Cravino, A
    Sariciftci, NS
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) : 1931 - 1943
  • [9] A novel polythiophene with pendant fullerenes: toward donor/acceptor double-cable polymers
    Cravino, A
    Zerza, G
    Maggini, M
    Bucella, S
    Svensson, M
    Andersson, MR
    Neugebauer, H
    Sariciftci, NS
    [J]. CHEMICAL COMMUNICATIONS, 2000, (24) : 2487 - 2488
  • [10] Design rules for donors in bulk-heterojunction tandem solar cells-towards 15 % energy-conversion efficiency
    Dennler, Gilles
    Scharber, Markus C.
    Ameri, Tayebeh
    Denk, Patrick
    Forberich, Karen
    Waldauf, Christoph
    Brabec, Christoph J.
    [J]. ADVANCED MATERIALS, 2008, 20 (03) : 579 - +
1234