The gem-dimethyl effect revisited

被引：119

作者：

Bachrach, Steven M. ^{[1
]}

机构：

[1] Trinity Univ, Dept Chem, San Antonio, TX 78212 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 06期

关键词：

D O I：

10.1021/jo702665r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Computation of the ring strain energy of 1,1-dimethylcyclobutane with a variety of methods reveals that there is no significant enthalpic component of the gem-dimethyl effect as measured by the ring strain energy.

引用

页码：2466 / 2468

页数：3

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