Microwave solid state synthesis and luminescence properties of green-emitting Gd2O2S:Tb3+ phosphor

被引:44
作者
He, Can [1 ]
Xia, Zhiguo [1 ,2 ]
Liu, Quanlin [2 ]
机构
[1] China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
[2] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
关键词
Phosphor; Optical properties; YTTRIUM OXYSULFIDE PHOSPHOR; NANOCRYSTALS; GLASSES; IONS; EU3+;
D O I
10.1016/j.optmat.2014.12.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Gd2-xO2S:xTb(3+) phosphors were prepared by the microwave solid state method, and its phase formation and morphologies were studied by the X-ray powder diffraction (XRD) and scanning electron microscope (SEM) techniques. The photoluminescence (PL) properties, cathodoluminescence (CL) properties and PL thermal stability of the samples were investigated, which indicated that better luminescence properties can be obtained via the microwave method compared to the conventional high temperature solid-state method. The composition-optimized Gd1.85O2S:15%Tb3+ exhibited strong green emission peaking at 546 nm upon excitation at 254 nm with the CIE coordinates of (0.238, 0.382). Different electric voltage and current dependent CL spectra investigations of Gd1.85O2S:15%Tb3+ phosphor shows similar green spectral profile as PL emission and it also demonstrates the good luminescence stability suggesting its potential application as green emission component in cathode ray tube (CRT). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:11 / 16
页数:6
相关论文
共 21 条
[1]   Size and Concentration Effects on the Photoluminescence of La2O2S:Eu3+ Nanocrystals [J].
Dai, Qilin ;
Song, Hongwei ;
Wang, Meiyuan ;
Bai, Xue ;
Dong, Biao ;
Qin, Ruifei ;
Qu, Xuesong ;
Zhang, Hui .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (49) :19399-19404
[2]   THEORY OF CONCENTRATION QUENCHING IN INORGANIC PHOSPHORS [J].
DEXTER, DL ;
SCHULMAN, JH .
JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (06) :1063-1070
[3]   Y2O2S : Eu3+ nanocrystals -: synthesis and luminescent properties [J].
Dhanaraj, J ;
Jagannathan, R ;
Trivedi, DC .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (07) :1778-1782
[4]   Effect of molten quenching temperature on glass-forming ability of nanoquasi-crystal-forming Zr-based metallic glasses [J].
Fan, C. ;
Liu, C. T. ;
Chen, G. ;
Chen, G. ;
Liaw, P. K. ;
Yan, H. G. .
SCRIPTA MATERIALIA, 2013, 68 (07) :534-537
[5]   Preparation of Y2O2S:Eu3+ phosphors by a novel decomposition method [J].
Guo, Chongfeng ;
Luan, Lin ;
Chen, Changhong ;
Huang, Dexiu ;
Su, Qiang .
MATERIALS LETTERS, 2008, 62 (4-5) :600-602
[6]   Lifetime for 5D4→7F5 emission in heavily Tb3+-doped superparamagnetic glasses [J].
Hayakawa, T ;
Sato, K ;
Yamada, K ;
Kamata, N ;
Nishi, N ;
Maruyama, F .
SYNTHETIC METALS, 1997, 91 (1-3) :355-356
[7]   2∞[Bi2Cl6(pyz)4]: A 2D-Pyrazine Coordination Polymer As Soft Host Lattice for the Luminescence of the Lanthanide Ions Sm3+, Eu3+, Tb3+, and Dy3+ [J].
Heine, Johanna ;
Wehner, Tobias ;
Bertermann, Ruediger ;
Steffen, Andreas ;
Mueller-Buschbaum, Klaus .
INORGANIC CHEMISTRY, 2014, 53 (14) :7197-7203
[8]   The phosphorescent properties of Er3+ in Gd2O2S by two-step absorption [J].
Hu, Lanying ;
Yan, Bin ;
Zhang, Jiahua ;
Wang, Xiaojun .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (23) :7519-7522
[9]   The effect of terbium concentration on the luminescent properties of yttrium oxysulfide phosphor for FED application [J].
Kang, C. C. ;
Liu, R. S. .
JOURNAL OF LUMINESCENCE, 2007, 122 :574-576
[10]   Microwave synthesis of a photocatalytically active SnO-based material [J].
Kuznetsova, S. A. ;
Pichugina, A. A. ;
Kozik, V. V. .
INORGANIC MATERIALS, 2014, 50 (04) :387-391