Methyl 4-(3-chlorophenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate

被引:2
作者
Li, YL [1 ]
Du, BX [1 ]
Wang, XS [1 ]
Zhang, MM [1 ]
Zeng, ZS [1 ]
机构
[1] Xuzhou Normal Univ, Dept Chem, Xuzhou, Peoples R China
关键词
D O I
10.1107/S1600536805012821
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C-20(22)3(H)ClNO, was synthesized by the reaction of 3-chlorobenzaldehyde, 5,5-dimethyl-1,3-cyclo-hexanedione and methyl 2-aminocrotonate in an ionic liquid medium. The X-ray analysis reveals that the nitrogen-containing ring adopts a boat conformation and the cyclohexene ring has a half-chair conformation. Intermolecular N-HO bonds in the structure lead to the formation of chains.
引用
收藏
页码:O1634 / O1636
页数:3
相关论文
共 11 条
[1]   4-ARYLDIHYDROPYRIDINES, A NEW CLASS OF HIGHLY-ACTIVE CALCIUM-ANTAGONISTS [J].
BOSSERT, F ;
MEYER, H ;
WEHINGER, E .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (09) :762-769
[2]  
Jacobson R, 1998, Private communication to Rigaku Corporation
[3]  
Kappe CO, 1997, TETRAHEDRON, V53, P2803
[4]  
REINHARD B, 2003, PHARMACOLOGY, V69, P171
[5]  
*RIG, 1999, CRYST CLEAR
[6]  
*RIG MSC, 2003, CRYST STRUCT
[7]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR
[8]   PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].
SHELDRICK, GM .
ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473
[9]  
Wasserscheid P, 2000, ANGEW CHEM INT EDIT, V39, P3772, DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO
[10]  
2-5