Geochronology and Geochemistry of the MAX Porphyry Mo Deposit and its Relationship to Pb-Zn-Ag Mineralization, Kootenay Arc, Southeastern British Columbia, Canada

被引:70
作者
Lawley, C. J. M. [1 ]
Richards, J. P. [1 ]
Anderson, R. G. [2 ]
Creaser, R. A. [1 ]
Heaman, L. M. [1 ]
机构
[1] Univ Alberta, Dept Earth & Atmospher Sci, Edmonton, AB T6G 2E3, Canada
[2] Geol Survey Canada, Vancouver, BC V6B 5J3, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
RE-OS GEOCHRONOLOGY; U-PB; FLUID-INCLUSION; MOLYBDENUM DEPOSIT; GOLD DEPOSIT; TROUT LAKE; CU-AU; COPPER; SYSTEM; SOLUBILITY;
D O I
10.2113/econgeo.105.6.1113
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The MAX porphyry Mo deposit is located at the northern end of the Kootenay arc in southeastern British Columbia, Canada. Molybdenum mineralization is genetically related to the variably altered Trout Lake granodiorite stock, which has lithogeochemical affinities to the low fluorine, calc-alkaline, granodiorite-hosted porphyry Mo deposit type. Three molybdenite samples from early and late Mo-bearing veins yield Re-Os dates that overlap within analytical error, with a weighted average age of 80.3 +/- 0.2 Ma. These dates are in close agreement with two Pb-206/U-238 weighted average zircon ages for phases of the Trout Lake stock at 80.3 +/- 1.6 and 79.2 +/- 1.0 Ma, indicating that crystallization of the stock and hydrothermal molybdenite formation were coeval and likely cogenetic. 40Ar/39Ar plateau ages for primary biotite in igneous dikes, secondary biotite in early potassic alteration, and muscovite in late phyllic alteration range from SO to 76 Ma. The younger 40Ar/39Ar plateau ages may reflect unusually slow cooling of the magmatic-hydrothermal system or a late thermal disturbance. Pb-Zn-Ag vein deposits are common throughout the Kootenay arc and several such veins are located within and proximal to the MAX porphyry Mo deposit. The presence of rare molybdenite associated with sphalerite and argentiferous galena in sonic of these Pb-Zn-Ag veins suggests that they represent a late-stage event related to the MAX magmatic-hydrothermal system. Fluid inclusions in quartz from Mo and Pb-Zn-Ag veins are similar and can be divided into two compositional groups: type 1, aqueous liquid-rich fluid inclusions; and type 2, aqueous-carbonic liquid-rich fluid inclusions. Pressure-corrected (1.4-1.7 kbar) trapping temperatures of typical type 1 inclusions from Mo-bearing veins range from 430 degrees to 460 degrees C, and for Pb-Zn-Ag veins, from 335 degrees to 365 degrees C. The ranges of salinity (0-12 wt % NaCl equiv) in fluid inclusions from both vein types are almost identical, and type 2 inclusions from both vein types contain similar amounts of CO2 (avg X-CO2, = 0.08) with traces of CH4. The similarity of chemistry in the two vein types suggests a genetic link between porphyry Mo mineralization and adjacent Pb-Zn-Ag deposits. However, muscovite from the alteration halo around a Pb-Zn-Ag vein within the MAX deposit yielded a 40Ar/39Ar plateau age of 72.2 +/- 0.5 Ma. This date is significantly younger than the similar to 80 Ma age of porphyry magmatism and Mo mineralization, suggesting either that this event is in fact unrelated to porphyry Mo mineralization at 80 Ma, or that the K-Ar isotope system has been disturbed by a later thermal event. The MAX porphyry Mo deposit is located at the northern end of the Kootenay arc in southeastern British Columbia, Canada. Molybdenum mineralization is genetically related to the variably altered Trout Lake granodiorite stock, which has lithogeochemical affinities to the low fluorine, calc-alkaline, granodiorite-hosted porphyry Mo deposit type. Three molybdenite samples from early and late Mo-bearing veins yield Re-Os dates that overlap within analytical error, with a weighted average age of 80.3 +/- 0.2 Ma. These dates are in close agreement with two Pb-206/U-238 weighted average zircon ages for phases of the Trout Lake stock at 80.3 +/- 1.6 and 79.2 +/- 1.0 Ma, indicating that crystallization of the stock and hydrothermal molybdenite formation were coeval and likely cogenetic. 40Ar/39Ar plateau ages for primary biotite in igneous dikes, secondary biotite in early potassic alteration, and muscovite in late phyllic alteration range from SO to 76 Ma. The younger 40Ar/39Ar plateau ages may reflect unusually slow cooling of the magmatic-hydrothermal system or a late thermal disturbance. Pb-Zn-Ag vein deposits are common throughout the Kootenay arc and several such veins are located within and proximal to the MAX porphyry Mo deposit. The presence of rare molybdenite associated with sphalerite and argentiferous galena in sonic of these Pb-Zn-Ag veins suggests that they represent a late-stage event related to the MAX magmatic-hydrothermal system. Fluid inclusions in quartz from Mo and Pb-Zn-Ag veins are similar and can be divided into two compositional groups: type 1, aqueous liquid-rich fluid inclusions; and type 2, aqueous-carbonic liquid-rich fluid inclusions. Pressure-corrected (1.4-1.7 kbar) trapping temperatures of typical type 1 inclusions from Mo-bearing veins range from 430 degrees to 460 degrees C, and for Pb-Zn-Ag veins, from 335 degrees to 365 degrees C. The ranges of salinity (0-12 wt % NaCl equiv) in fluid inclusions from both vein types are almost identical, and type 2 inclusions from both vein types contain similar amounts of CO2 (avg X-CO2, = 0.08) with traces of CH4. The similarity of chemistry in the two vein types suggests a genetic link between porphyry Mo mineralization and adjacent Pb-Zn-Ag deposits. However, muscovite from the alteration halo around a Pb-Zn-Ag vein within the MAX deposit yielded a 40Ar/39Ar plateau age of 72.2 +/- 0.5 Ma. This date is significantly younger than the similar to 80 Ma age of porphyry magmatism and Mo mineralization, suggesting either that this event is in fact unrelated to porphyry Mo mineralization at 80 Ma, or that the K-Ar isotope system has been disturbed by a later thermal event.
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页码:1113 / 1142
页数:30
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