The ternary system H2O-NH4NO3-Al(NO3)3.: II.: The polythermic diagram up to 100 °C

被引：0

作者：

Kaddami, M

El Allali, S

Ferhat, M

Counioux, JJ

机构：

[1] Ecole Natl Ind Minerale, Lab Physicochim Mat, Agdal Rabat, Morocco

[2] Fac Sci Rabat, Chim Phys Lab, Rabat, Morocco

[3] Univ Lyon 1, CNRS, URA 116, Lab Physicochim Minerale 2, F-69622 Villeurbanne, France

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1998年 / 95卷 / 07期

关键词：

ternary system; invariant transformations; H2O-NH4NO3-Al(NO3)(3);

D O I：

10.1051/jcp:1998337

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The ternary system H2O-NH4NO3-Al(NO3)(3). II. The polythermic diagram up to 100 degrees C. The solid-solid equilibrium diagram of H2O-NH4NO3-Al(NO3)(3 .)6H(2)O composition field is completely established up to 100 degrees C. A quasibinary eutectic and ten ternary isobar invatiant transformations are observed by thermal analysis and fully characterized: liq. E <----> ice + NH4NO3 V + Al(NO3)(3 .)9H(2)O at - 33.6 degrees C at - 33.6 degrees C liq. T-1 + NH4NO3 IV <----> ice + NH4NO3 V at - 18.8 degrees C at - 18.8 degrees C liq. Q(1) + Al(NO3)(3 .)8H(2)O alpha <----> Al(NO3)(3 .)9H(2)O + NH4NO3 IV at - 12.3 degrees C liq. T-2 + NH4NO3 IV <----> Al(NO3)(3 .)9H(2)O + NH4NO3 at - 18.8 degrees C liq. T-3 + NH4NO3 IV <----> NH4NO3 V (binary) at 32 degrees C liq. T-4 + NH4NO3 III <----> Al(NO3)(3 .)8H(2)O alpha + NH4NO3 IV at 32 degrees C liq. T-5 + Al(NO3)(3 .)8H(2)O beta <----> Al(NO3)(3 .)8H(2)O alpha + Al(NO3)(3 .)9H(2)O at 37.0 degrees C liq. T-6 + Al(NO3)(3 .)8H(2)O beta <----> Al(NO3)(3 .)8H(2)O alpha + NH4NO3 III at 37.0 degrees C liq. Q(2) + Al(NO3)(3 .)6H(2)O <----> Al(NO3)(3 .)8H(2)O beta +NH4NO3 III at 41.0 degrees C liq. T-7 + Al(NO3)(3 .)8H(2)O gamma <----> Al(NO3)(3 .)8H(2)O beta + Al(NO3)(3 .)9H(2)O at 51.0 degrees C liq. T-8 + Al(NO3)(3 .)8H(2)O gamma <----> Al(NO3)(3 .)6H(2)O beta + Al(NO3)(3 .)8H(2)O beta at 51.0 degrees C.

引用

页码：1731 / 1747

页数：17

共 50 条

[31] -25, -15, -5, 10, 25 and 40°C isotherms of the ternary H2O-Al(NO3)3-Zn(NO3)2 system
Laallam, L
Kaddami, M
EL Allali, S
Missali, L
Tenu, R
Berthet, J
Counioux, JJ
ANNALES DE CHIMIE-SCIENCE DES MATERIAUX, 2004, 29 (04): : 133 - 142
[32] NANO3-NH4NO3-MG(NO3)2-H2O SYSTEM AT 25-DEGREES-C
TIMOSHENKO, YM
CHEKMAREVA, IN
ZHURNAL NEORGANICHESKOI KHIMII, 1989, 34 (10): : 2711 - 2713
[33] Study of 25°C isotherm of the quasi-quaternary system H2O-Zn(NO3)2•6H2O-Cu(NO3)2•3H2O-NH4NO3 I -: Isopleth-4 of mass% NH4NO3, 8 mass% NH4NO3, 10 mass% Zn(NO3)2
Ibnlfassi, A
Kaddami, M
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 79 (01) : 123 - 128
[34] SOLUBILITY IN LA(NO3)3-C6H5NH2.HNO3-H2O SYSTEM
GORSHUNOVA, VP
ZHURAVLE.EF
ZHURNAL NEORGANICHESKOI KHIMII, 1970, 15 (05): : 1422 - +
[35] AL(NO3)3-UO2(NO3)2-H2O SYSTEM AT 25-DEGREES-C
MEDKOV, BK
PETROV, MR
ROSLYAKOVA, ON
ZHURNAL NEORGANICHESKOI KHIMII, 1987, 32 (07): : 1783 - 1784
[36] NH4NO3-MG(NO3)2-CE(NO3)3-H2O SYSTEM AT 25DEGREESC
SHEVCHUK, VG
MITINA, NK
ZHURNAL NEORGANICHESKOI KHIMII, 1976, 21 (07): : 1943 - 1947
[37] Modeling the solubility surfaces of the phase diagram Mg(NO3)2-Al(NO3)3-H2O
Mançour-Billah, S
Hmaïdouch, LA
El Hadek, M
Cohen-Adad, R
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 62 (03): : 781 - 795
[38] AL(NO3)3-AL2(SO4)3-H2O SYSTEM AT 25-DEGREES-C
PETROV, MR
ROSLYAKOVA, ON
BLAU, TV
ZHURNAL NEORGANICHESKOI KHIMII, 1982, 27 (10): : 2707 - 2708
[39] SOLUBILITY IN CO(NO3)2-NH4NO3-H2O SYSTEM AT 20 DEGREES
ALYMOVA, LN
KORF, DM
LEBEDEVA
ZHURNAL PRIKLADNOI KHIMII, 1970, 43 (02) : 458 - &
[40] The heats of formation of Al(NO3)(3) 6H(2)O and Al(NO3)(3) 9H(2)O
Young, FE
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1944, 66 : 777 - 779

← 1 2 3 4 5 →