Synthesis of nickel(II)-di(5-chloro-2-methylphenyl)carbazonate and its adduct formation with heterocyclic nitrogen bases

被引：6

作者：

Hiremath, SA

Bhat, RB

机构：

[1] Department of Chemistry, Karnatak University

来源：

TRANSITION METAL CHEMISTRY | 1996年 / 21卷 / 04期

关键词：

D O I：

10.1007/BF00139028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex has been synthesized and characterized by elemental and spectral analysis. The Ni-II chelate forms adducts with heterocyclic nitrogen bases, which were characterized spectrophotometrically in solution. Bidentate and unsaturated monodentate bases form hexacoordinate adducts with 1:1 and 1:2 metal:ligand stoichiometries, respectively, whilst saturated nitrogen bases form pentacoordinate adducts with 1:1 stoichiometry. The results are discussed in terms of basicities and steric properties of the bases.

引用

页码：327 / 330

页数：4

共 16 条

[1]

AKAIWA H, 1969, J CHEM SOC JAPAN PUR, V90, P186

[2]

AKAIWA H, 1968, ANAL CHIM ACTA, V40, P102

[3]

Flaschka H. A., 1959, EDTA TITRATIONS, P79

[4] CRYSTAL AND MOLECULAR STRUCTURE OF PENTACOORDINATED COPPER(2) COMPLEX BIS(ACETYLACETONATO)QUINOLINECOPPER(2) [J].