Total Synthesis of (-)- Basiliskamide A and NMR Studies on the Conversion of Basiliskamide A to Basiliskamide B

被引：5

作者：

Dias, Luiz C. ^{[1
]}

Goncalves, Caroline C. S. ^{[1
]}

机构：

[1] Univ Estadual Campinas, Inst Quim, BR-13083970 Campinas, SP, Brazil

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2010年 / 21卷 / 10期

基金：

巴西圣保罗研究基金会;

关键词：

antifungal polyketides; Stille cross-coupling; aldol reaction; NMR studies; ALPHA-AMINO ALDEHYDES; CHIRAL ALLYLSILANE; ALLYLTRICHLOROSTANNANE ADDITIONS; STEREOSELECTIVE-SYNTHESIS; STILLE REACTION; NAGAHAMIDE-A; ANTIFUNGAL; PALLADIUM; STEREOCHEMISTRY; ANTIBACTERIAL;

D O I：

10.1590/S0103-50532010001000030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe herein our approach to the total synthesis of the antifungal polyketide (-)- basiliskamide A, as well as H-1 NMR studies on the migration of the cinnamoyl side chain of basiliskamide A to form basiliskamide B in CDCl3 solution.

引用

页码：2012 / 2016

页数：5

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